Journal ArticleDOI
Etude de l'obtention d'enoxysilanes par action du triethylsilane sur des cetones enolisables, aliphatiques ou cyclaniques, en presence de catalyseurs au nickel
Reads0
Chats0
TLDR
In this article, the preparation of alkoxysilanes and alkenoxideysilane has been achieved by the reaction of enolizable aliphatic or cyclic ketones with triethylsilane in the presence of nickel catalysts.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1975-02-11. It has received 33 citations till now. The article focuses on the topics: Triethylsilane.read more
Citations
More filters
Journal ArticleDOI
Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes
TL;DR: Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of C═O bonds of aldehydes and ketones in the presence of other functional groups as discussed by the authors.
Journal ArticleDOI
A new practical synthesis of silyl enol ethers
TL;DR: In this article, a new route to enoxysilanes is described from simple enolizable aldehydes or ketones, using the trimethylchlorosilane-sodium iodide-tertiary amine reagent in acetonitrile.
Journal ArticleDOI
Synthesis, Characterization, and Reactivity, in the C−H Bond Activation of Cycloalkanes, of a Silica-Supported Tantalum(III) Monohydride Complex: (⋮SiO)2TaIII−H
TL;DR: In this article, the reaction of Ta[CH2C(CH3)3] with a silica dehydroxylated at 500 °C has been previously reported to produce a mixture of surface Si−H groups.
Journal ArticleDOI
Transition metal-catalyzed hydrosilylation of carbonyl compounds and imines. a review
TL;DR: Transition METAL-CATALYZED HYDROSILYLATION of CARBONYL COMPOUNDS and IMINES as mentioned in this paper is an example of a transition-metal-catalanguage approach.
Journal ArticleDOI
Base-free dehydrogenative coupling of enolizable carbonyl compounds with silanes.
TL;DR: A dehydrogenative coupling between enolizable carbonyl compounds and equimolar amounts of triorganosilanes catalyzed by a tethered ruthenium complex with a Ru-S bond is reported.
References
More filters
Journal ArticleDOI
Infra-red spectra and structure of methyl vinyl ether
Noel L. Owen,N. Sheppard +1 more
Journal ArticleDOI
Factors affecting the out-of-plane hydrogen deformation frequencies in olefins and their derivatives
W.J. Potts,Richard A. Nyquist +1 more
TL;DR: In this article, various infrared absorption group frequency correlations for out-of-plane hydrogen deformations of substituted ethylenes are reviewed, and it is shown that the CH 2 wag motion of vinyl and vinylidene type substituted polyethylenes behave in an analogous manner.
Journal ArticleDOI
Hydrogen-Halogen Exchange Reactions of Triethylsilane. A New Rearrangement of Neopentyl Chloride1
Journal ArticleDOI
O-silyl-substituted enols
Carl R. Krüger,Eugene G. Rochow +1 more
TL;DR: In this article, it was shown that bis(trimethylsilyl)amide reacts with non-enolisable carbonyl compounds to yield silyl-substituted imines and sodium silanolate.
Journal ArticleDOI
Sur Quelques aspects de la reactivite des hydrogenosilanes en chimie organique
TL;DR: In this paper, a condition for faire intervenir un catalyseur efficace, on s'apen;oit que les hydrogenosilanes reagissent souvent facilement avec les composes organiques.
Related Papers (5)
Action de trialkylsilanes sur les aldehydes aliphatiques : II. Etude de l'obtention d'enoxysilanes en presence de certains catalyseurs au nickel
Emile Frainnet,Rolland Bourhis +1 more