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Evaluated activity and osmotic coefficients for aqueous solutions: iron chloride and the bi‐univalent compounds of nickel and cobalt
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A critical evaluation of the mean activity and osmotic coefficients in aqueous solutions of iron chloride, nickel chloride, perchlorate, and nitrate and twenty-nine bi-univalent compounds of cobalt at 298.15 K is presented in this paper.Abstract:
A critical evaluation of the mean activity and osmotic coefficients in aqueous solutions of iron chloride, nickel chloride, perchlorate, and nitrate and twenty‐nine bi‐univalent compounds of cobalt at 298.15 K is presented. Osmotic coefficients were calculated from direct vapor pressure measurements, from isopiestic measurements, from freezing point depression measurements, and from vapor pressure osmometry measurements. Given are empirical coefficients for three different correlating equations, obtained by a weighted least squares fit of the experimental data, and tables consisting of the activity coefficients of the compounds, the osmotic coefficients and activity of water, and the excess Gibbs energy of the solution as functions of the molality for each electrolyte system. The literature coverage is through the computerized version of Chemical Abstracts of April 1979.read more
Citations
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Two-parameter debye-hückel approximation for the evaluation of mean activity coefficients of 109 electrolytes
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Evaluated activity and osmotic coefficients for aqueous solutions: thirty‐six uni‐bivalent electrolytes
TL;DR: A critical evaluation of the mean acivity and osmotic coefficients in aqueous solutions of thirty-five uni-bivalent electrolytes at 298.15 K is presented in this article.
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Evaluation of the optimum composition of neutral-carrier membrane electrodes with incorporated cation-exchanger sites
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Thermodynamics of the disproportionation of adenosine 5'-diphosphate to adenosine 5'-triphosphate and adenosine 5'-monophosphate. I. Equilibrium model.
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References
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Manual of symbols and terminology for physicochemical quantities and units
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Computer Programs for the Evaluation of Activity and Osmotic Coefficients
Bert R. Staples,Ralph L. Nuttall +1 more
TL;DR: A number of specialized computer programs have been developed for the purposes of calculating thermodynamic properties directly from experimental data and for subsequent data manipulation, including non-linear least squares fitting of the data to empirical or semi-empirical equations that describe the function over a range of compositions, temperatures or other parameters.
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