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The Physical Chemistry of Electrolytic Solutions
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The article was published on 1963-01-01 and is currently open access. It has received 3191 citations till now.read more
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On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
TL;DR: In this paper, the temperature variation of the fractionation of oxygen in exchange reactions between dissolved carbonate and water and between calcite and water was calculated on theoretical grounds, and checked experimentally.
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Free Volume and Entropy in Condensed Systems III. Entropy in Binary Liquid Mixtures; Partial Molal Entropy in Dilute Solutions; Structure and Thermodynamics in Aqueous Electrolytes
Henry S. Frank,Marjorie W. Evans +1 more
TL;DR: The first and second papers in this series, which make it possible to interpret entropy data in terms of a physical picture, are applied to binary solutions, and equations are derived relating energy and volume changes when a solution is formed to the entropy change for the process as discussed by the authors.
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Transport in proton conductors for fuel-cell applications: simulations, elementary reactions, and phenomenology.
TL;DR: Theoretical Methodologies and Simulation Tools, and Poisson−Boltzmann Theory, and Phenomenology of Transport inProton-Conducting Materials for Fuel-CellApplications46664.2.1.
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The solubility of nitrogen, oxygen and argon in water and seawater
TL;DR: In this paper, precise data on the solubilities of nitrogen, oxygen and argon in distilled water and seawater are fitted to thermodynamically consistent equations by the method of least squares.
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Solute perturbation of protein fluorescence. The quenching of the tryptophyl fluorescence of model compounds and of lysozyme by iodide ion.
TL;DR: The results of the model compound study provide evidence for a mechanism that follows the classical Stern-Volmer law (1919), predominantly involving collisional quenching, and illustrate the importance of local charge and solvent viscosity.