Journal ArticleDOI
Excess properties of binary mixtures. Secondary amine + n-alkane systems
Reads0
Chats0
TLDR
In this paper, two microcalorimetric techniques were used, one based on the measurement of integral enthalpies using a Calvet micro-calorimeter, the other on the determination of partial excess enthpies by continuous-flow conduction micro calcorimetry with deconvolution of the response.About:
This article is published in Thermochimica Acta.The article was published on 1983-10-01. It has received 12 citations till now. The article focuses on the topics: Binary system.read more
Citations
More filters
Journal ArticleDOI
A comparative study of thermodynamic properties of n-alkane or cycloalkane mixtures with aliphatic linear or heterocyclic, molecules containing the same functional groups
TL;DR: In this article, the data available in the literature for the excess Gibbs energies, excess enthalpies, activity coefficients at infinite dilution, and excess heat capacities of heterocyclic tertiary amines, secondary amines and ethers + n-alkanes or + cycloalkanes are examined on the basis of DISQUAC, an extended quasichemical group contribution theory.
Journal ArticleDOI
Interactions of ionic liquids and acetone: thermodynamic properties, quantum-chemical calculations, and NMR analysis.
TL;DR: Spectroscopic and COSMO-RS results indicated that acetone, as a polar compound with strong hydrogen bond acceptor character, in most cases, establishes favorable hydrogen bonding with ILs, and quantum-chemical calculations by using molecular clusters of acetone and IL species provided additional evidence of the main role played by hydrogen bonding in the behavior of systems containing ILs and HB acceptor compounds.
Journal ArticleDOI
Thermodynamics of ketone + amine mixtures: Part II. Volumetric and speed of sound data at (293.15, 298.15 and 303.15) K for 2-propanone + dipropylamine, + dibutylamine or + triethylamine systems
Iván Alonso,Víctor Alonso,Ismael Mozo,Isaías García de la Fuente,Juan Antonio González,José Carlos Cobos +5 more
TL;DR: In this article, the authors used a vibrating tube densimeter and sound analyser Anton Paar model DSA-5000 to measure the densities, ρ, and speeds of sound, u, of 2-propanone+dipropylamine, + dibutylamine or + triethylamine systems at (293.15, 298.15 and 303.15) K and atmospheric pressure.
Journal ArticleDOI
Thermodynamics of (ketone + amine) mixtures. Part VI. Volumetric and speed of sound data at (293.15, 298.15, and 303.15) K for (2-heptanone + dipropylamine, +dibutylamine, or +triethylamine) systems
TL;DR: In this paper, the authors used a vibrating tube densimeter and sound analyzer Anton Paar model DSA-5000 to measure the properties of 2-heptanone and triethylamine (TEA) systems.
Journal ArticleDOI
Thermodynamics of mixtures with strongly negative deviations from Raoult's law. XI. Densities, viscosities and refractives indices at (293.15–303.15) K for cyclohexylamine + 1-propanol, or +1-butanol systems
TL;DR: In this article, the thermophysical properties densities, ρ, kinetic viscosities, ν, and refractive indices, nD, have been measured at atmospheric pressure and at (293.15-303.15) K for the mixtures cyclohexylamine+1-propanol, or +1-butanol.
References
More filters
Journal ArticleDOI
Thermodynamics of Nonelectrolyte Solutions - x-y-t relations in a Binary System
Otto Redlich,A. T. Kister +1 more
Journal ArticleDOI
An isothermal displacement calorimeter for endothermic enthalpies of mixing
TL;DR: An isothermal displacement calorimeter has been constructed and used to measure the enthalpies of mixing for the systems benzene+cyclohexane at 25 °C and benzene + carbon tetrachloride at 25°C as mentioned in this paper.
Journal ArticleDOI
Enthalpies of mixing of n-hexane + cyclohexane at 25 °C
K.N. Marsh,R.H. Stokes +1 more
TL;DR: The enthalpy of mixing of n-hexane+cyclohexane has been measured at 25 °C as a contribution to the establishment of reliable values for use in testing Enthalpy-of-mixing calorimeters as mentioned in this paper.
Journal ArticleDOI
Thermodynamik flüssiger Mischungen von Kohlenwasserstoffen mit verwandten Substanzen
TL;DR: The theory of mixtures with associating component(s) is critically surveyed in this paper, where experimental results on several selected systems are presented and their relative importance as to a systematic program concerning the thermodynamics of organic mixtures is clarified.
Journal ArticleDOI
Description thermodynamique des melanges moleculaires: extension du domaine d'application de la calorimetrie a conduction par deconvolution de la reponse instrumentale
TL;DR: In this article, a new application of conduction flow calorimetry to the study of molecular mixtures is described, where the deconvolution of the caloric output has the advantage that partial molar enthalpies of mixing of the added component can be measured directly at high dilution.