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Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry

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TLDR
In this paper, nanometer-scale electrodes have been used for the measurement of electron-transfer rate constants, k_(het), that are two orders of magnitude faster than k(het) values accessible with any other electrochemical method.
Abstract
Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, k_(het), that are two orders of magnitude faster than k_(het) values accessible with any other electrochemical method.

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A nano-lead dioxide-composite electrochemical sensor for the determination of chemical oxygen demand

TL;DR: In this article , a novel nano-PbO2-composite electrochemical sensor was fabricated, and its electrochemical sensing properties for COD detection were investigated, which exhibited a linear range from about 500 −9000 mg·L−1.
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Poly(ethyleneoxide-block-methylmethacrylate) derived recessed nanodisc electrode array as an ultrasensitive electrochemical sensing platform for immunosensor

TL;DR: In this paper , the synthesis of amphiphilic diblock copolymer poly(ethylene oxide-block-methylmethacrylate) (PEO-b-PMMA) using atom transfer radical polymerization and demonstrate its application for the fabrication of recessed nanodisk-array electrode (RNE) as a platform for protein detection.
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Journal ArticleDOI

Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry

TL;DR: Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies that have enabled the measurement of electron-transfer rate constants, khet, that are two orders of magnitude faster than khet values accessible with any other electrochemical method.
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