Journal ArticleDOI
Facile product isolation from organostannane reductions of organic halides
J. E. Leibner,John Jacobus +1 more
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This article is published in Journal of Organic Chemistry.The article was published on 1979-02-01. It has received 112 citations till now.read more
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Journal ArticleDOI
The Stille Reaction, 38 Years Later
TL;DR: The first now-named Stille reaction was published 38 years ago, and the last comprehensive revision of this catalysis was in 2004, and since then, the knowledge of the different steps of the three possible (and sometimes competing) reaction pathways (cyclic, open, and ionic) has been almost completed by synergistic experimental and theoretical studies as mentioned in this paper.
Journal ArticleDOI
Allylic protecting groups and their use in a complex environment part II: Allylic protecting groups and their removal through catalytic palladium π-allyl methodology
Journal ArticleDOI
Triethylborane-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides
Katsukiyo Miura,Yoshifumi Ichinose,Kyoko Nozaki,Keigo Fugami,Koichiro Oshima,Kiitiro Utimoto +5 more
TL;DR: The reduction of organic halides with tributyltin hydride in the presence of a catalytic amount of triethylborane has been studied in this paper, and the reduction of alkenyl halides and alkyl bromides with n-Bu3SnH-Et3B system was not so effective.
Journal ArticleDOI
Significant Enhancement of the Stille Reaction with a New Combination of Reagents—Copper(I) Iodide with Cesium Fluoride
TL;DR: The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction and a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Book ChapterDOI
4.1 – Radical Addition Reactions
TL;DR: In the last decade, the application of radical addition reactions to problems in fine synthesis has grown from the level of a curiosity to that of a major reaction class as discussed by the authors, in part due to the high level of understanding of organic radicals that has been provided by fundamental research on structure and reactivity.
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A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium
David Milstein,J. K. Stille +1 more
Atom transfer cyclization reactions of .alpha.-iodo esters, ketones, and malonates: examples of selective 5-exo, 6-endo, 6-exo, and 7-endo ring closures
Dennis P. Curran,Chi Tai Chang +1 more