Journal ArticleDOI
Facile regeneration of carbonyl compounds by oxidative cleavage of hydrazones using dioxiranes
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This article is published in Journal of Organic Chemistry.The article was published on 1993-12-01. It has received 14 citations till now. The article focuses on the topics: Organic peroxide & Hydrazone.read more
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Synthesis of α-Keto Esters and Amides via Oxidative Cleavage of Cyanoketophosphoranes by Dimethyldioxirane
Journal ArticleDOI
Steroids: reactions and partial synthesis
TL;DR: The article reviews the progress in the chemistry of the steroids that was published between January and December, 2000 and covers the reactions and partial syntheses of estrogens, androgens, pregnanes, cholic acid derivatives, cholestanes and vitamin D analogues.
Journal ArticleDOI
Formaldehyde dimethylhydrazone: A new neutral reagent for nucleophilic hydroformylation and hydrocyanation
TL;DR: The readily available title compound smoothly adds to nitroolefins without any need of base or catalysis, giving β-nitrodimethylhydrazones 3 in high yields as mentioned in this paper.
Journal ArticleDOI
High-yield synthesis of nitriles by oxidation of aldehyde N,N-dimethylhydrazones with dimethyldioxirane
A. Altamura,Lucia D'Accolti,Antonia Detomaso,Anna Dinoi,Michele Fiorentino,Caterina Fusco,Ruggero Curci +6 more
TL;DR: Using dimethyldioxirane, the selective transformation of aldehyde N, N -dimethyl-hydrazones into the corresponding nitriles was achieved in high yield and under mild conditions as mentioned in this paper.