Journal ArticleDOI
Facile synthesis of silver(i)-carbene complexes. useful carbene transfer agents
TLDR
In this paper, the crystal structure of compound 1 revealed that linear [Ag(Et2-Bimy)2]+ and [AgBr2]- groups were associated through a short AgI−AgI contact (2.956 A).About:
This article is published in Organometallics.The article was published on 1998-02-12. It has received 1033 citations till now. The article focuses on the topics: Carbene & Molar conductivity.read more
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N-heterocyclic carbenes: a new concept in organometallic catalysis.
TL;DR: N-Heterocyclic carbenes have become universal ligands in organometallic and inorganic coordination chemistry as mentioned in this paper, and they not only bind to any transition metal, be it in low or high oxidation states, but also to main group elements such as beryllium, sulfur, and iodine.
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Heterocyclic Carbenes: Synthesis and Coordination Chemistry
TL;DR: New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclized isocyanides have been developed recently.
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Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.
TL;DR: The fascinating story of olefin (or alkene) metathesis began almost five decades ago, when Anderson and Merckling reported the first carbon-carbon double-bond rearrangement reaction in the titanium-catalyzed polymerization of norbornene.
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Organocatalytic ring-opening polymerization.
Nahrain E. Kamber,and Wonhee Jeong,Robert M. Waymouth,Russell C. Pratt,and Bas G. G. Lohmeijer,James L. Hedrick +5 more
TL;DR: This paper presents the design of highly efficient families of “living” polymerization strategies for the synthesis of block, graft, and star polymers through controlled methods for the controlled synthesis of dendritic macromolecules.
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Recent homogeneous catalytic applications of chelate and pincer N-heterocyclic carbenes
Eduardo Peris,Robert H. Crabtree +1 more
TL;DR: In this paper, the use of N-heterocyclic carbene ligands (NHCs) based on imidazolium ions and related heterocycles has emerged as an alternative to phosphines in the design of new organometallic catalysts.
References
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The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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A stable crystalline carbene
TL;DR: Synthese, structure et caracterisation du (1,3-bis [1-adamantyl]-2, 3-dihydro)-2,carbenoimidazole prepare par deprotonation du chlorure de (1 3-bis] [1]- imidazolium as discussed by the authors.
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Metal Complexes of N‐Heterocyclic Carbenes—A New Structural Principle for Catalysts in Homogeneous Catalysis
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Homoatomic d10–d10 Interactions: Their Effects on Structure and Chemical and Physical Properties
TL;DR: The distinction between valence electrons and essentially inactive core electrons is the basis of many classifying concepts in chemistry as discussed by the authors, and it has recently been recognized that this is an oversimplification and should, at least in some areas, be modified.
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