Journal ArticleDOI
Formation, structure, and reactivities of 1:1 adducts between quadricyclane and (η5-cyclopentadienyl)(1,2-diphenyl- or -dimethoxycarbonyl-1,2-ethenedithiolato)rhodium(III)
Mitsushiro Nomura,Hiroshi Hatano,Tetsuji Fujita,Yutaka Eguchi,Ryuuko Abe,Mikako Yokoyama,Chikako Takayama,Takeo Akiyama,Akira Sugimori,Masatsugu Kajitani +9 more
TLDR
In this article, the structure of the adduct 2a was re-investigated and determined by X-ray structural analysis, and the rhodiadithiolene complexes and those adducts showed the catalytic activities for the thermal isomerization from Q to norbornadiene (NBD).About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2004-03-15. It has received 18 citations till now. The article focuses on the topics: Quadricyclane & Norbornadiene.read more
Citations
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Journal ArticleDOI
Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions
TL;DR: This review surveys the different ligands that have been used to support palladium-catalyzed aerobic oxidation reactions and describes mechanistic insights into the role played by the ancillary ligand.
Journal ArticleDOI
Dinuclear Cp* cobalt complexes of the 1,2,4,5-benzenetetrathiolate bischelating ligand.
Mitsushiro Nomura,Marc Fourmigué +1 more
TL;DR: The X-ray structures of the dinuclear complex 1 and the mononuclear complexes 4a and 6 were determined, and they are all characterized by Cp* . . . btt face-to-face intermolecular interactions, leading to a recurrent 4-fold symmetry motif.
Journal ArticleDOI
Reactivity and electrochemical behavior of ruthenium dithiolene complexes with coordinatively unsaturated metal centers: cycloaddition and dimerization reactions
TL;DR: In this paper, the ruthenium dithiolene complexes (arene)Ru{S 2 C 2 (COOMe) 2 }] (arenes = C 6 H 6 (1a), C 6 Me 6 ( 1c )) were synthesized, and the equilibrium between complex 1a and the corresponding dimer was confirmed in solution.
Journal ArticleDOI
Organometallic dithiolene complexes of the group 8–10 metals: Reactivities, structures and electrochemical behavior
TL;DR: It is concluded that the 'coexistence of aromaticity and unsaturation' in the metallacycle mediates the diverse chemical reactions.
Journal ArticleDOI
Catalytic production of sulfur heterocycles (dihydrobenzodithiins): a new application of ligand-based alkene reactivity
Daniel J. Harrison,Ulrich Fekl +1 more
TL;DR: Activation of bis-o-phenylene tetrasulfide to render it a practical benzodithiete equivalent for [4+2] cycloadditions with alkenes has been achieved with catalytic amounts of Mo.
References
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Journal ArticleDOI
Preparation, Reactions, and Structure of Bisdithio-α-diketone Complexes of Nickel, Palladium, and Platinum1,2
G. N. Schrauzer,V. P. Mayweg +1 more
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Coordination compounds with delocalized ground states. Transition metal derivatives of dithiodiketones and ethylene-1,2-dithiolates (metal dithienes)
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Steric Influence on the Reactivity of the (o-Carboranedithiolato)iridium(III) Complex [Ir(η5-C5Me5)(η2-S2C2B10H10)]: New Types of Addition Reactions Involving Cyclometalation or Isomerization†
TL;DR: In this article, the reactivity of the mononuclear 16-electron iridadithiolene ring complex Cp*Ir(S2C2B10H10) (1) toward alkynes, a diazoalkane, and quadricyclane has been investigated.
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Synthesis and Chemical Properties of Metalladithiolene and Metalladithiazole Rings. Unique Reactions Due to Coexistence of Aromaticity and Unsaturation
TL;DR: In this article, the synthesis and unique chemical properties of metalladithiolene rings (especially in [CpM(S2C2R1R2)]-type complexes) found by our research group are reviewed.