Journal ArticleDOI
Free radicals in the synthesis of medium-sized rings
TLDR
In this paper, free radical chemistry in the synthesis of seven-to-nine-membered rings is presented, and applications of free radical chemiques in the synthesisation of seven to nine-memered rings are discussed.About:
This article is published in Tetrahedron.The article was published on 1999-07-30. It has received 161 citations till now. The article focuses on the topics: Radical.read more
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Palladium-catalyzed cross-coupling reactions in total synthesis.
TL;DR: In this Review, highlights of a number of selected syntheses are discussed, demonstrating the enormous power of these processes in the art of total synthesis and underscore their future potential in chemical synthesis.
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Recent developments in asymmetric multicomponent reactions.
TL;DR: Significantly broadened scopes, new techniques, more environmentally benign methods and entirely novel MCRs reflect the increasingly inventive paths that synthetic chemist follow in this field of asymmetric multicomponent reactions.
Journal ArticleDOI
Palladiumkatalysierte Kreuzkupplungen in der Totalsynthese
Kyriacos C. Nicolaou,Kyriacos C. Nicolaou,Paul G. Bulger,Paul G. Bulger,David Sarlah,David Sarlah +5 more
TL;DR: In this paper, the authors discuss the effect of leistungsfahigen Reaktionen on the Potenzial f f zukunftige chemischen Synthesen unterstreichen, i. e.g., palladiumkatalysierten Kreuzkupplungen.
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Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems
TL;DR: In this paper, the authors studied the effect of intermolecular radical cyclizations and multicomponent radical cascades in solution, which are initiated by intermolescular radical addition to C-C triple bond in alkynes as well as to related C?N triple bonds in nitriles and isonitriles, arranged according to the atom that carries the unpaired electron in the attacking radical and cover main group IV-VI elements.
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