Journal ArticleDOI
Further considerations on entropy estimations of actinide compounds: AmCl3 and AmCl2
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TLDR
In this article, the standard entropy S 0 (298.15 K) of AmCl 2 has been estimated by extrapolation of the available data for the lanthanide(II) chlorides to the actinide series.About:
This article is published in Journal of Nuclear Materials.The article was published on 2002-03-01. It has received 10 citations till now. The article focuses on the topics: Standard molar entropy.read more
Citations
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Journal ArticleDOI
The Thermodynamic Properties of the f-Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides
Rudy J. M. Konings,Ondrej Beneš,Attila Kovács,Dario Manara,David Sedmidubský,Lev Gorokhov,V. S. Iorish,V.S. Yungman,E. Shenyavskaya,E. L. Osina +9 more
TL;DR: A comprehensive review of the thermodynamic properties of the oxide compounds of the lanthanide and actinide elements is presented in this article, where the available literature data for the solid, liquid, and gaseous state have been analyzed and recommended values are presented.
Journal ArticleDOI
The Thermodynamic Properties of the f-Elements and Their Compounds. I. The Lanthanide and Actinide Metals
Rudy J. M. Konings,Ondrej Beneš +1 more
TL;DR: A critical review of the thermodynamic properties of the lanthanide and actinide elements is presented in this paper, where the available literature data for the solid, liquid, and gaseous state have been collected and recommended values are presented.
Journal ArticleDOI
Electrochemical behaviour of americium ions in LiCl–KCl eutectic melt
Jérôme Serp,Pierre Chamelot,S. Fourcaudot,Rudy J. M. Konings,Rikard Malmbeck,Carole Pernel,Carole Pernel,Jean-Claude Poignet,Jean Rebizant,Jean-Paul Glatz +9 more
TL;DR: In this article, the electrochemical properties of AmCl 3 in a molten LiCl-KCl eutectic, at a temperature range of 733-833 K, were investigated.
Book ChapterDOI
Thermodynamic properties of the lanthanide(III) halides
Rudy J. M. Konings,Attila Kovács +1 more
TL;DR: In this article, the thermodynamic properties of the lanthanide (III) halides were discussed and a distinct difference was observed between the heat capacity and entropy of the hexagonal and monoclinic lanthanides that clearly correlates with a difference in molar volume between the two modifications.
Radiation Safety Information Computational Center
TL;DR: The September 2003 edition, of the International Handbook of Evaluated Criticality Safety Benchmark Experiments is scheduled to be ready for distribution on CD-ROM near the end of September.
References
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BookDOI
The chemistry of the actinide elements
TL;DR: In this paper, the authors present a comparative analysis of the actinide elements and their properties, including properties of organoactinide compounds having metal-carbon bonds only to?-bonded ligands.
Journal ArticleDOI
Thermodynamic Properties of U, Np, Pu, and Am in Molten LiCl‐KCl Eutectic and Liquid Cadmium
J. J. Roy,L. F. Grantham,D. L. Grimmett,S. P. Fusselman,C.L. Krueger,T.S. Storvick,Tadashi Inoue,Yoshiharu Sakamura,Noriaki Takahashi +8 more
TL;DR: In this paper, the Gibbs free energy of actinide chlorides in LiCl-KCl/Cd system was obtained as part of the development of an electrochemical pyropartitioning process to remove actinides from PUREX waste residues.
Journal ArticleDOI
A systematic analysis of the spectra of trivalent actinide chlorides in D3h site symmetry
TL;DR: In this paper, the optical spectra of actinide ions in the compound AnCl and doped into single crystal LaCl were interpreted in terms of transitions within 5f{sup N} configurations.
Journal ArticleDOI
Thermodynamic Properties for Rare Earths and Americium in Pyropartitioning Process Solvents
S. P. Fusselman,J. J. Roy,D. L. Grimmett,L. F. Grantham,C.L. Krueger,C. R. Nabelek,T.S. Storvick,Tadashi Inoue,Takatoshi Hijikata,Kensuke Kinoshita,Yoshiharu Sakamura,Koichi Uozumi,Tsutomu Kawai,Noriaki Takahashi +13 more
TL;DR: In this paper, the authors obtained standard potential data for Y, La, Ce, Pr, and Gd in molten LiCl-KCl and activity coefficients for Cd and Bi.
Journal ArticleDOI
The enthalpies of formation of lanthanide compounds: I. LnCl3(cr), LnBr3(cr) and LnI3(cr)
E.H.P. Cordfunke,R.J.M. Konings +1 more
TL;DR: The enthalpies of formation of trichlorides, tribromides and tri-iodides have been evaluated from the experimental data available in literature as mentioned in this paper, and all experimental results have been re-calculated using a consistent set of the most recent auxiliary data.