Journal ArticleDOI
Ground states of conjugated molecules. XIX. Tautomerism of heteroaromatic hydroxy and amino derivatives and nucleotide bases
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This article is published in Journal of the American Chemical Society.The article was published on 1970-05-01. It has received 125 citations till now. The article focuses on the topics: Tautomer.read more
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Photo-CIDNP in nucleic acid bases and their nucleotides induced by chlorpromazine and analogs.
TL;DR: Polarizations of the starting material of a mixture of aqueous chlorpromazine and different pyrimidine and purine bases and nucleotides show polarizations can be explained by means of an electron transfer mechanism from CPZ to the bases.
Journal ArticleDOI
A comparative study on vibrational, conformational and electronic structure of 1,2-dimethyl-5-nitroimidazole and 2-methyl-5-nitroimidazole
TL;DR: The conformational analyses were performed and the energies of the different possible conformers were determined, and the influences of nitro and methyl groups on the skeletal modes have been investigated.
Journal ArticleDOI
New heteroaromatic compounds—XXXIV: Bisboratriazaroles
TL;DR: A number of bis -2,1,3,4-boratriazaroles have been prepared by reacting boronic acids or their derivatives with bis -amidrazones and their properties studied as mentioned in this paper.
Journal ArticleDOI
Convenient preparations and Michael reactions of 4-fluoroalkylated but-2-en-4-olides
TL;DR: Trifluoromethyl, heptafluoropropyl, and chlorodifluorsophyl substituted but-2-en-4-olide have been prepared both from 2-trimethylsiloxyfuran by fluoroalkylation with the corresponding bis(fluoroalkanoyl) peroxide and from 2fluoroalkylfuran by oxidation with m-nitrobenzenesulfonyl peroxide as mentioned in this paper.
Journal ArticleDOI
Role of topological charge stabilization in protomeric tautomerism.
TL;DR: It was found that the branching of amino or hydroxyl groups significantly contributes to the stability of major species through the first- and second-order perturbations with respect to the isoelectronic hydrocarbon.
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