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Journal ArticleDOI

Ignition and Combustion of Boron Particles and Clouds

Merrill K. King
- 01 Jul 1982 - 
- Vol. 19, Iss: 4, pp 294-306
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TLDR
In this article, the authors defined the Steins an-Boltzmann constant as the product of the density-diffusivity product of boron and boric oxide.
Abstract
PE Nomenclature = heat capacity of the gases = boron heat capacity = oxide heat capacity = heat absorbed by reaction of B2O3 with H2O = heat absorption associated with surface reaction(s) (per unit mass of boron) = heat of vaporization of B2O3 = particle burning mass flux = heat release associated with gas-phase reaction(s) (per unit mass of oxygen) = heat release of B + B2O3 reaction = particle radius = molar rate of boron consumption = molar evaporation rate of boric oxide = molar rate of removal of B2O3 by water reaction = time = particle temperature = effective surroundings radiation temperature = particle surface temperature — ambient temperature = oxide layer thickness = ambient oxygen mass fraction = surroundings absorptivity = particle emissivity = boron density = boric oxide density = density-diffusivity product = Stef an-Boltzmann constant

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Citations
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Journal ArticleDOI

Ignition and combustion of boron particles

TL;DR: In this article, a comprehensive survey of the previous experimental work, theoretical models, and chemical kinetics studies of single boron particles is presented, along with up-to-date research findings which represent two major research needs strongly recommended by previous researchers.
Journal ArticleDOI

Direct combustion of recyclable metal fuels for zero-carbon heat and power

TL;DR: In this article, a metal-fuelled zero-carbon heat engine is proposed for power generation in which metal fuels are burned with air in a combustor to provide clean, high-grade heat.
Journal ArticleDOI

Kinetics of high-temperature B/O/H/C chemistry

TL;DR: In this article, the sensitivity of the species concentration profiles to the chosen initial species speciation (for a fixed number of moles of each element) is nearly independent of this speciation for reaction times greater than a few microseconds, suggesting that the identity of a species evolving from a reacting boron particle is not eritical to the surrounding gas phase combustion process.
Journal ArticleDOI

Oxidation of small boron cluster ions (B + 1-13 ) by oxygen

TL;DR: In this article, the absolute cross sections for all ionic products formed in reactions of B+1−13 with oxygen have been measured under single collision conditions, at collision energies from 0.25 to 10 eV.
Journal ArticleDOI

A physical and chemical interpretation of boron particle combustion

TL;DR: In this paper, the combustion of boron is considered from both physical and chemical points of view, and the overall combustion process is separated into an ignition phase, during which the particle is covered by a layer of BORON oxide, and a clean particle burning phase.
References
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Book

Combustion, Flames and Explosions of Gases

TL;DR: The second edition of this book has been in short supply for some time and the authors have decided in favor of a reprint of the book rather than an extensive revision at this time.
Journal ArticleDOI

Combustion of Boron Particles at Atmospheric Pressure

TL;DR: In this paper, single particles of pure crystalline boron were injected into streams of hot oxidizing gases, generated by a gas-burner, at atmospheric pressure, and the panicle combustion process was described.
Journal ArticleDOI

Boron Particle Ignition in Hot Gas Streams

TL;DR: In this paper, a model of boron ignition treating the inhibiting effect of a boric oxide coating has been developed, converted to difference form and programmed for computer solution for determination of ignition limits and ignition times.
Journal ArticleDOI

Boron Ignition and Combustion in Air-Augmented Rocket Afterburners

TL;DR: In this paper, it was shown that ignition of the boron particles, inhibited by the presence of a coating of oxide, is likely the controlling process, and the prediction of whether or not a given particle will ignite and, if it will, the time required for ignition.
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