Journal ArticleDOI
Impedance studies of the growth of porous magnetite films on carbon steel in high temperature aqueous systems
J.R. Park,Digby D. Macdonald +1 more
TLDR
In this article, the growth of porous magnetite on carbon steel in high temperature chloride solution has been studied using the a.c. impedance technique, and the frequency dispersion of the impedance of the growing film has been successfully accounted for by a finite transmission line model.About:
This article is published in Corrosion Science.The article was published on 1983-01-01. It has received 135 citations till now. The article focuses on the topics: Corrosion & Polarization (electrochemistry).read more
Citations
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Journal ArticleDOI
Reflections on the history of electrochemical impedance spectroscopy
TL;DR: The history of electrochemical impedance spectroscopy (EIS) is briefly reviewed, starting with the foundations laid by Heaviside in the late 19th century in the form of Linear Systems Theory (LST), leading to the development of models for the electrified interface as mentioned in this paper.
Journal ArticleDOI
Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces
TL;DR: In this article, the influence of surface inhomogeneities on corrosion processes is demonstrated by electrochemical impedance spectroscopy (EIS), and experimental impedance data obtained in different systems are discussed on the basis of transfer function analysis.
Journal ArticleDOI
Electrochemical Impedance Spectroscopy of Metal Oxide Electrodes for Energy Applications
TL;DR: The metal oxides have been of great importance to the development of energy conversion and storage technologies including heterojunction solar cells, Li-ion batteries, and electrocatalysts/photocatalys.
Journal ArticleDOI
Influence of the boundaries in the impedance of porous film electrodes
TL;DR: In this paper, an enhanced model for the impedance of porous film electrodes is presented, where the local impedances at the boundaries represent a frequency-dependent response of the blocking of ionic and electronic charge carriers at the two faces of the electrode region.
Journal ArticleDOI
Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments
TL;DR: In this paper, the corrosion behavior of TiN coated type 316 stainless steel (SS) was investigated in simulated proton exchange membrane fuel cell environments, i.e. 0.01 M HCl + 0.1 M Na2SO4 solutions bubbled with pure oxygen and hydrogen gases, respectively, by using electrochemical measurement techniques.
References
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Journal ArticleDOI
Advances in Electrochemistry and Electrochemical Engineering
P. Delahay,Ashok K. Vijh +1 more
Journal ArticleDOI
External Reference Electrodes for Use in High Temperature Aqueous Systems
TL;DR: In this paper, the thermal cell (25°C) as a function of the concentration of and temperature are reported, combined with isothermal potentials for the silver-silver chloride electrode at elevated temperatures to calibrate external electrodes as pseudothermodynamic standards for the investigation of electrochemical processes in high temperature aqueous systems.
Journal ArticleDOI
The Electrochemistry of Iron in lM Lithium Hydroxide Solution at 22° and 200°C
Digby D. Macdonald,D. Owen +1 more
Book ChapterDOI
Electrochemical impedance techniques in corrosion science
D. D. Macdonald,M. C. H. Mckubre +1 more
TL;DR: In this paper, a review of the use of impedance techniques in corrosion science is presented, focusing on defining the type of data that is required in corrosion studies, and then comparing different methods for generating therequired information by electrochemical impedance methods.
Related Papers (5)
Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves
Milton Stern,A. L. Geary +1 more