scispace - formally typeset
Open AccessBook

Infrared and Raman Spectra of Inorganic and Coordination Compounds

TLDR
In this article, the normal modes of vibration are illustrated and corresponding vibrational frequencies are listed for each type, including diatomic, triatomic, fouratomic, five-atomic, six-atomic and seven-atomic types.
Abstract
Inorganic molecules (ions) and ligands are classified into diatomic, triatomic, four-atomic, five-atomic, six-atomic, and seven-atomic types, and their normal modes of vibration are illustrated and the corresponding vibrational frequencies are listed for each type. Molecules of other types are grouped into compounds of boron, carbon, silicon, nitrogen, phosphorus, and sulfur, and the structures and infrared (IR)/Raman spectra of select examples are shown for each group. Group frequency charts including band assignments are shown for phosphorus and sulfur compounds. Other group frequency charts include hydrogen stretching frequencies, halogen stretching frequencies, oxygen stretching and bending frequencies, inorganic ions, and metal complexes containing simple coordinating ligands. Keywords: inorganic compounds; coordination compounds; diatomic molecules (ligands); triatomic molecules (ligands); four-atomic molecules (ligands); five-atomic molecules (ligands); six-atomic molecules (ligands); seven-atomic molecules (ligands); boron compounds; carbon compounds; silicon compounds; nitrogen compounds; phosphorus compounds; sulfur compounds; group frequency charts

read more

Content maybe subject to copyright    Report

Citations
More filters
Journal ArticleDOI

The interaction of water with solid surfaces: Fundamental aspects

TL;DR: In this paper, the authors compare and discuss recent experimental and theoretical results in the field of H2O-solid interactions, and emphasize studies of low (submonolayer) coverages of water on well-characterized, single-crystal surfaces of metals, semiconductors and oxides.
Journal ArticleDOI

A room-temperature organometallic magnet based on Prussian blue

TL;DR: In this paper, a room-temperature organometallic magnet was synthesized by combining a hexa-cyanometalate [M(CN)6]q− with a Lewis acid Lp+.
Journal ArticleDOI

Continuous deformations in random networks

TL;DR: In this paper, the authors examine the differences between covalent random networks with high and low average coordination and make rigorous assumptions about the number of continuous deformations (i.e., zero frequency modes) allowed within the network.
Journal ArticleDOI

Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica

TL;DR: In this article, the authors show that direct grafting of an organometallic complex onto the inner walls of mesoporous silica MCM-41 generates a shape-selective catalyst with a large concentration of accessible, well spaced and structurally well defined active sites.