Journal ArticleDOI
Infrared matrix isolation studies of the 1:1 molecular complexes of hydrogen chloride and hydrogen bromide with substituted cyclopropanes
TLDR
Caracterisation des complexes formes entre HCl ou HBr and les cyclopropanes portant un substituant electroattracteur: Br, CN, CH 2 Br, CHOHCH 3 ou COCH 3 as mentioned in this paper.Abstract:
Caracterisation des complexes formes entre HCl ou HBr et les cyclopropanes portant un substituant electroattracteur: Br, CN, CH 2 Br, CHOHCH 3 ou COCH 3read more
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Journal ArticleDOI
Matrix isolation studies of reactive intermediate complexes
TL;DR: In this paper, a composes d'addition formes entre acides and bases of Lewis, par exemple SiF 4 •NH 3, are presented.
Journal ArticleDOI
Matrix Isolation Infrared and ab Initio Study of the 1:1 Complexes of Bromocyclopropane with NH3 and (CH3)3N: Evidence for a Novel C−H···N Hydrogen Bond
TL;DR: In this paper, a cyclopropane substituent was used as a proton donor for the first time in argon matrices at 16 K. Ab initio calculations yield an essentially linear BrC−H−NH3 hydrogen bond with a C−H···N distance of 2.301 A and a hydrogen bond energy of 2,35 kcal/mol.
Journal ArticleDOI
Matrix Isolation Infrared Spectroscopic and Density Functional Theory Study of the 1:1 Complex of Bromocyclohexane with NH3: Evidence for a Weak C-H-N Hydrogen Bond
Kyle R. Hess,Cindy Samet +1 more
TL;DR: The hydrogen-bonded bromocyclohexane-ammonia complex has been isolated and characterized for the first time in argon matrices at 16 K as discussed by the authors.
Journal ArticleDOI
The halogens and hydrogen
TL;DR: In this article, aspects cinetique, energetique et structural de divers composes organiques halogenes, and synthese bibliographique is used to define a bibliographic index.