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Inhibition of hydrogen absorption by submonolayer deposition of metals on platinum

S. H. Cadle, +1 more
- 01 Nov 1971 - 
- Vol. 43, Iss: 13, pp 1858-1862
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This article is published in Analytical Chemistry.The article was published on 1971-11-01. It has received 79 citations till now. The article focuses on the topics: Deposition (chemistry) & Platinum.

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Citations
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Arrangement of ad-atoms of various kinds on substrates: Part I. Platinum substrate

TL;DR: The number of platinum sites occupied by a foreign atom was determined with use of pulse technique as mentioned in this paper, and the foreign atoms included are Cu, Ag, Cd, Hg, In, Tl, Ge, Sn, Pb, Se, Te, As, Sb, and Bi The approximate value is 1 for the first two, 2 for the next nine and 3 for the others Silver and copper ad-atoms are closely packed on the platinum surface, but the other elements are arranged on the surface leaving geometrical room on it even when a complete mon
Journal ArticleDOI

The electrochemical behavior of ad-atoms and their effect on hydrogen evolution

TL;DR: In this article, the number of the pairs (nPt−Pt) decrease, thus resulting the decrease of the recombination of adsorbed hydrogen hence the reduction of the hydrogen evolution rate.
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Electrochemical surface science: The study of monolayers of ad-atoms and solvent molecules at charged metal interfaces

TL;DR: In this paper, the potential of the metal electrode at the interface of a metal and a liquid has been studied in the field of electrochemical surface science, where the electrode potential has been used as an independent variable to control surface charge density, coverage by Faradaically deposited ad-atoms, co-adsorption of cations or anions and solvent dipole orientation.
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The study of solid surfaces by electrochemical methods

TL;DR: The basic concepts of electrochemistry at the solid-electrolyte interface are discussed in this article with special emphasis on surface physical aspects, including the optical reflectance of metal electrodes and the electric charge on the surface, both of which can easily be controlled by the voltage applied to the electrochemical cell.
References
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Electrode for sensing fluoride ion activity in solution

Martin S Frant, +1 more
- 23 Dec 1966 - 
TL;DR: Electrodes constructed from single-crystal sections of rare earth fluorides respond to fluoride ion activity over more than five orders of magnitude and show a high selectivity for fluoride over other common anions.
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Simultaneous and independent potentiostatic control of two indicator electrodes. Application to the copper(II)/copper(I)/copper system in 0.5M potassium chloride at the rotating ring-disk electrode

TL;DR: Simultaneous and independent potentiostatic control of rotating ring and disk electrode and application to CuII/CuI/Cu system.
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