Journal ArticleDOI
Inorganic derivatives of iron sulfide thiolate dimers and tetramers: synthesis and properties of the halide series [Fe2S2X4]2- and [Fe4S4X4]2- (X = chlorine, bromine, iodine)
TLDR
In this paper, the authors present a new 2-bzw. 4kernigen Dianionen isolierbar in the form of a R4 N-Salze isolier bar.Abstract:
Die Komplexe (I) bzw. (V) reagieren mit den Benzoylhalogeniden (II) in AcCN glatt zu den neuen 2- bzw. 4kernigen Dianionen (III) bzw. (VII), die in Form ihrer R4 N-Salze isolierbar sind.read more
Citations
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Book ChapterDOI
Trinuclear Cuboidal and Heterometallic Cubane-Type Iron–Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology
TL;DR: The cuboidal and heterometal cubane-type species afford new structural and reactivity themes in both inorganic chemistry and biology as discussed by the authors, which is well supported by consideration of just four of the major discoveries in the field in the last decade.
Journal ArticleDOI
Use of preassembled iron/sulfur and iron/molybdenum/sulfur clusters in the stepwise synthesis of potential analogs for the Fe/Mo/S site in nitrogenase
Journal ArticleDOI
Structural Conversions of Synthetic and Protein-Bound Iron–Sulfur Clusters
Richard H. Holm,Wayne Lo +1 more
TL;DR: An extensive body of core conversions, many of which have not been recognized as such, are presented including those in biological systems and all structural core types are depicted, and all core conversions are diagrammatically summarized.
Journal ArticleDOI
Catalytic Reduction of Hydrazine to Ammonia with MoFe(3)S(4)-Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase.
TL;DR: Results are consistent with results obtained previously in the laboratory and strongly suggest that N(2)H(4) activation and reduction occur at the Mo site of the [(L)MoFe(3)S( 4)Cl(3)](2)(-)(, 3)(-) clusters.