Journal ArticleDOI
Irreversible processes in the electrochemical reduction of polythiophenes. Chemical modifications of the polymer and charge-trapping phenomena
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In this article, the authors investigated reversible changes occurring in the electrochemical reduction of polythiophenes in acetonitrile have been investigated by cyclic voltammetry (CV), UV-Vis and IR spectroscopy.About:
This article is published in Synthetic Metals.The article was published on 1995-06-01. It has received 106 citations till now. The article focuses on the topics: Cyclic voltammetry & Qualitative inorganic analysis.read more
Citations
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Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices
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Stability of n-type doped conducting polymers and consequences for polymeric microelectronic devices
TL;DR: In this paper, the authors derived the stability requirements on electrode potentials of n-type doped conducting polymers and compared the predictions with experimental data on stability of polymers, and showed that an electrode potential of about 0 to + 0.5 V (SCE) is required for stable polymers.
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Electrochemistry of Conducting Polymers—Persistent Models and New Concepts†
TL;DR: Electropolymerization in Novel Electrolytic Media 4745: Influence of the Polymerization Technique, Influence of Experimental Conditions, and Specific Phenomena of n-Doping.
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Design of Narrow-Bandgap Polymers. Syntheses and Properties of Monomers and Polymers Containing Aromatic-Donor and o-Quinoid-Acceptor Units
TL;DR: A series of novel monomers and polymers containing aromatic-donor and o-quinoid-acceptor units was prepared, and the relationship between their spectral and electrochemical properties and their structures was investigated as discussed by the authors.
Journal ArticleDOI
Three-Step Redox in Polythiophenes: Evidence from Electrochemistry at an Ultramicroelectrode
Xiwen Chen and,Olle Inganäs +1 more
TL;DR: In this article, the transition between polaron, bipolaron, and metallic states of poly(3,4-ethylenedioxythiophene) (PEDOT) was detected using in situ UV−VIS−NIR spectroscopy.
References
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Electrochemical studies of some conducting polythiophene films
TL;DR: In this paper, a property-structure correlation between monomers and their corresponding polymers is obtained by systematic variation of the chemical structure of the monomers, with conductivity of the order of 1 ohm/sup-1/ cm/sup -1/
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Rectifying interfaces using two-layer films of electrochemically polymerized vinylpyridine and vinylbipyridine complexes of ruthenium and iron on electrodes
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The electronic and electrochemical properties of poly(isothianaphthene)
TL;DR: The physical and electronic properties of poly(isothianaphthene) are reported in this paper, including initial characterization, electrochemical cyclic voltammetry, spectroscopy, and transport properties.
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Organic conducting polymers derived from substituted thiophenes as electrochromic material
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Organic Metals and Semiconductors: The Chemistry of Polyacetylene, (CH)x, and Its Derivatives.
TL;DR: Both cis and trans-forms of polyacetylene, (CH)x, may be prepared as silvery, flexible, polycrystalline, semiconducting films as mentioned in this paper, and the cis-films can be stretched to over three times their original length with partial alignment of the fibrils.