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LXIII.—The interaction between alkyl Grignard reagents and antimony trichloride

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This article is published in Journal of The Chemical Society (resumed).The article was published on 1930-01-01. It has received 21 citations till now. The article focuses on the topics: Antimony trichloride & Beta-Hydride elimination.

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Journal ArticleDOI

Coordination chemistry of stibine and bismuthine ligands

TL;DR: The synthesis of the common monodentate and bidentate stibines and bismuthines, and of multidentates containing one or more antimony or Bismuth donor are briefly reviewed in this article.
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Synthesis and Configuration of Some Triorganoantimony (V) Chelates of Tetradentate Schiff Bases

TL;DR: A series of Schiff base complexes of organoantimony (V) having formula R3SbL (R = phenyl or methyl, L = dibasic tetradentate ligands with the ONNO donor system) have been synthesized as discussed by the authors.
Journal ArticleDOI

Synthesis and Characterization of the Complex Triorganoantimony(V) Cations, R3SbL2+ and R3Sb(L-L)2+

TL;DR: Pentacoordinate cationic complexes of the types [R3SbL′2]Y2(I) and [R 3Sb(L-L))Y 2(II), (where R = CH3, C6H5 and P-CH3C6H4 L′ = DMSO, TPAO and TPPO; L-L = bipy and en; Y = BF4 or BPh4) have been synthesized and characterized by elemental analysis as mentioned in this paper.
Journal ArticleDOI

Preparation of Primary Alkylantimony Compounds

TL;DR: In contrast with the lighter group-V elements, access to primary alkyl compounds of antimony is impeded by the low thermal stability of the hydrides.
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