Journal ArticleDOI
Matrix isolation study of the complexes of small ring heterocycles: Part 1. Complexes of the hydrogen halides with ethylene oxide and related species
TLDR
In this paper, the spectral properties of the 1:1 and 1:2 saturated heterocycles with the free hydrogen halide were investigated, and the results for the furan complexes cannot be rationalized in this fashion.About:
This article is published in Journal of Molecular Structure.The article was published on 1985-03-01. It has received 13 citations till now. The article focuses on the topics: Hydrogen halide & Matrix isolation.read more
Citations
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Journal ArticleDOI
Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes
TL;DR: The available data on main group (Groups 12-18) Lewis acid base, donor-acceptor, charge transfer and van der Waals complexes stabilised by matrix isolation techniques are presented, tabulated and evaluated in conjunction with data from complementary gas phase experiments and computational chemistry as discussed by the authors.
Journal ArticleDOI
Matrix isolation studies of reactive intermediate complexes
TL;DR: In this paper, a composes d'addition formes entre acides and bases of Lewis, par exemple SiF 4 •NH 3, are presented.
Journal ArticleDOI
Ab initio and matrix isolation study of the acetylene–furan dimer
Elsa Sanchez-Garcia,Artur Mardyukov,Adem Tekin,Rachel Crespo-Otero,Luis A. Montero,Wolfram Sander,Georg Jansen +6 more
TL;DR: In this paper, the second-order Moller-Plesset (MP2) level of theory was used to identify five acetylene-furan dimer structures using ab initio calculations.
Journal ArticleDOI
Furan-formic acid dimers: an ab initio and matrix isolation study.
TL;DR: The most stable furan-FA dimer was identified as the major product of the aggregation by comparison of the experimental IR spectrum with calculated IR spectra of a variety of complexes.
Journal ArticleDOI
Infrafred matrix isolation study of the hydrogen-bonded complexes between ethylene oxide and three hydrogen halides
P. Bernadet,L. Schriver +1 more
TL;DR: In this paper, a bifid structure of the (HX) 2 - ethylene oxide species was characterized, on the basis of H/D isotopic dilution, which the two HX molecules are equivalent.
References
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Partially deuterated water dimers: Microwave spectra and structure
Jamiu A. Odutola,T. R. Dyke +1 more
TL;DR: In this paper, the effects of large amplitude vibrational motion have been estimated and the equilibrium geometry should lie within the above limits with χa and φd equal to zero.
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Ion Cyclotron Resonance Spectroscopy
TL;DR: Ion cyclotron resonance spectroscopy has met with such wide acceptance that research groups utilizing this relatively new experimental technique now likely outnumber research groups which have used more traditional techniques, such as high pressure mass spectrometry, for the study of ion-molecule reactions as discussed by the authors.
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Gas phase basicities and relative proton affinities of compounds between water and ammonia from pulsed ion cyclotron resonance thermal equilibriums measurements
J. F. Wolf,R. H. Staley,I. Koppel,M. Taagepera,R. T. McIver,Jesse L. Beauchamp,Robert W. Taft +6 more
TL;DR: The pulsed ion cyclotron resonance method for precise determinations of proton transfer equilibrium constants has been applied to 46 carbon, nitrogen, oxygen, phosphorus, sulfur, arsenic, and selenium bases, with duplicating overlapping sequences, to obtain the relative proton affinities of water and ammonia as mentioned in this paper.
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Molecular complexes of the hydrogen halides studied by matrix isolation infrared spectroscopy
TL;DR: Spectroscopic studies of base-hydrogen halide complexes are reviewed in this paper, including previously unpublished data for complexes of hydrogen chloride and hydrogen bromide with a variety of bases in argon matrices.