Journal ArticleDOI
Measurement of induction times for the formation of methane and ethane gas hydrates
TLDR
Experimental data on hydrate formation kinetics, including induction times for methane, ethane and a mixture of the two gases, are presented in this article, where the data were measured using a stirred batch reactor recording the pressure as a function of time at constant temperature.About:
This article is published in Chemical Engineering Science.The article was published on 1993-02-01. It has received 153 citations till now. The article focuses on the topics: Induction period.read more
Citations
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Journal ArticleDOI
Deep sea NMR: Methane hydrate growth habit in porous media and its relationship to hydraulic permeability, deposit accumulation, and submarine slope stability
Robert L. Kleinberg,C. Flaum,Douglas D. Griffin,Peter G. Brewer,G. E. Malby,Edward T. Peltzer,J. P. Yesinowski +6 more
TL;DR: In this paper, nuclear magnetic resonance (NMR) measurements have been made on methane hydrate-bearing sandstones and the relative permeability to water, as determined by an NMR-based correlation, was significantly reduced.
Journal ArticleDOI
Gas hydrates in sustainable chemistry
Aliakbar Hassanpouryouzband,Aliakbar Hassanpouryouzband,Aliakbar Hassanpouryouzband,Edris Joonaki,Edris Joonaki,Mehrdad Vasheghani Farahani,Satoshi Takeya,Carolyn D. Ruppel,Jinhai Yang,Niall J. English,Judith M. Schicks,Katriona Edlmann,Hadi Mehrabian,Zachary M. Aman,Bahman Tohidi +14 more
TL;DR: This review summarizes the different properties of gas hydrates as well as their formation and dissociation kinetics and then reviews the fast-growing literature reporting their role and applications in the aforementioned fields, mainly concentrating on advances during the last decade.
Journal ArticleDOI
Induction time in crystallization of gas hydrates
Dimo Kashchiev,Abbas Firoozabadi +1 more
TL;DR: In this article, the initial stage of one-component gas hydrates in aqueous solutions is analyzed and the temporal evolution of the volume of hydrate crystallized and the moles of gas consumed are determined.
Journal ArticleDOI
A mass transport limited model for the growth of methane and ethane gas hydrates
Per Skovborg,Peter Rasmussen +1 more
TL;DR: In this paper, a simplified model is proposed based on the assumption that the transport of gas molecules from the gas phase to the liquid water phase is the rate-determining step in the overall hydrate formation process.
Journal ArticleDOI
Induction phenomena in gas hydrate nucleation
TL;DR: In this paper, the metastable region for hydrate nucleation is discussed and the driving force for hydrates is defined, and the induction period data for the various hyddrates from a total of 93 hydrate formation runs were modelled as a function of the nucleation driving force.
References
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Journal ArticleDOI
Equilibrium constants from a modified Redlich-Kwong equation of state
TL;DR: In this article, a modified Redlich-Kwong equation of state is proposed, which can be extended successfully to multicomponent-VLE calculations for mixtures of nonpolar substances, with the exclusion of carbon dioxide.
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Dissociation Pressures of Gas Hydrates Formed by Gas Mixtures
W. R. Parrish,J. M. Prausnitz +1 more
Journal ArticleDOI
Kinetics of formation of methane and ethane gas hydrates
TL;DR: An intrinsic kinetic model with only one adjustable parameter is proposed for the formation of methane and ethane gas hydrates in this article, where the formation rate is proportional to the difference in the fugacity of the dissolved gas and the three-phase equilibrium fugacity at the experimental temperature.
Journal ArticleDOI
A kinetic study of methane hydrate formation
A. Vysniauskas,P.R. Bishnoi +1 more
TL;DR: In this paper, a semi-empirical model was formulated to correlate the experimental kinetic data, which revealed that the formation kinetics were dependent on the interfacial area, pressure, temperature and degree of supercooling.
Journal ArticleDOI
Thermodynamic and Molecular Properties of Gas Hydrates from Mixtures Containing Methane, Argon, and Krypton
TL;DR: In this article, the authors used experimental methane-krypton and methane-argon hydrate data to generate chemical-potential, enthalpy, and heat-capacity functions for Structure I hydrates for temperatures between -190/sup 0/ and 80/Sup 0/F (150 and 300 K) using a modified statistical model where the gas-water interactions were calculated from the spherical core Kihara intermolecular pair potential function.