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Journal ArticleDOI

Mechanical behavior assessment of sucrose using nanoindentation

K.J. Ramos, +1 more
- 01 Jul 2007 - 
- Vol. 22, Iss: 7, pp 2037-2045
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TLDR
In this paper, an experimental study of the elastic and plastic properties of single crystals of sucrose was carried out using nanoindentation, which can be considered to be a model material for both pharmaceutical excipients and explosives.
Abstract
An experimental study of the elastic and plastic properties of sucrose single crystals, which can be considered to be a model material for both pharmaceutical excipients and explosives, has been carried out using nanoindentation. Instrumented indentation was used to characterize the properties of both habit and cleavage planes on the (100) and (001) orientations; the elastic modulus on the (100) is 38 GPa, while the modulus on the (001) is 33 GPa. The hardness of sucrose is approximately 1.5 GPa. Nanoindentation enables assessment of the onset of plastic deformation on cleaved surfaces, and a maximum shear stress of 1 GPa can be supported prior to plastic deformation. The deformation in this material is crystallographically dependent, with pileup around residual indentation impressions showing evidence of preferential slip system activity.

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Citations
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Journal ArticleDOI

Nanoindentation in Crystal Engineering: Quantifying Mechanical Properties of Molecular Crystals

TL;DR: Through nanoindentation it is possible to correlate molecular-level properties such as crystal packing, interaction characteristics, and the inherent anisotropy with micro/macroscopic events such as desolvation, domain coexistence, layer migration, polymorphism, and solid-state reactivity.
Journal ArticleDOI

Interaction anisotropy and shear instability of aspirin polymorphs established by nanoindentation

TL;DR: In this article, nanoindentation is applied to the two polymorphs of aspirin to examine and differentiate their interaction anisotropy and shear instability, and different elastic moduli and hardness values are correlated with their crystal structures.
Journal ArticleDOI

Mechanical anisotropy in crystalline saccharin: nanoindentation studies

TL;DR: In this article, the nanoindentation technique has been employed to relate the mechanical properties of saccharin single crystals with their internal structure and to assess the mechanical anisotropy.
Journal ArticleDOI

Direct observation of plasticity and quantitative hardness measurements in single crystal cyclotrimethylene trinitramine by nanoindentation

TL;DR: In this article, deformation deformation beginning with elasticity and continuing through the elastic-plastic transition to incipient cracking has been investigated for (210, (021) and (001) oriented single crystals of the explosive cyclotrimethylene trinitramine, commonly known as “RDX”.
Journal ArticleDOI

New, High Efficiency Nonlinear Optical Chalcone Co-Crystal and Structure–Property Relationship

TL;DR: In this article, a co-crystal of (2E)-1-(4-chlorophenyl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one was grown using a slow evaporation solution.
References
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Journal ArticleDOI

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments

TL;DR: In this paper, the authors used a Berkovich indenter to determine hardness and elastic modulus from indentation load-displacement data, and showed that the curve of the curve is not linear, even in the initial stages of the unloading process.
MonographDOI

Contact Mechanics: Frontmatter

K. L. Johnson
Book

The Hardness of Metals

David Tabor
TL;DR: Hardness measurements with conical and pyramidal indenters as mentioned in this paper have been used to measure the area of contact between solids and the hardness of ideal plastic metals. But they have not yet been applied to the case of spherical indenters.
Journal ArticleDOI

Microindentations on W and Mo oriented single crystals: An STM study

TL;DR: In this article, the authors studied micron size indentations of Mo and W single crystals using the scanning tunneling microscopy (STM) and discussed the mechanism of plastic flow and the indentation size effect.
Journal ArticleDOI

The deformation behavior of ceramic crystals subjected to very low load (nano)indentations

TL;DR: In this article, a software-controlled hardness tester (Nanoindenter) operating in the load range 2-60 mN was used to characterize the deformation structures associated with these very small-scale hardness impressions.
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