Journal ArticleDOI
Metal-centered oxygen atom transfer reactions
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This article is published in Chemical Reviews.The article was published on 1987-12-01. It has received 868 citations till now. The article focuses on the topics: Physical organic chemistry & Organic reaction.read more
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Cell biology and molecular basis of denitrification.
TL;DR: Denitrification is intimately related to fundamental cellular processes that include primary and secondary transport, protein translocation, cytochrome c biogenesis, anaerobic gene regulation, metalloprotein assembly, and the biosynthesis of the cofactors molybdopterin and heme D1.
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Activation of c-h bonds by metal complexes
A. E. Shilov,Georgiy B. Shul'pin +1 more
TL;DR: In this article, it was shown that the same alkylhydridoplatinum(IV) complex is the intermediate in the reaction of ethane with platinum(II) σ-complexes.
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The Mononuclear Molybdenum Enzymes
TL;DR: It is now well-established that all molybdenum-containing enzymes other than nitrogenase fall into three large and mutually exclusive families, as exemplified by the enzymes xanthine oxidation, sulfite oxidase, and DMSO reductase; these enzymes represent the focus of the present account.
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Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts
TL;DR: In this paper, the authors dealt with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(III)complexes.
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Probing structure-function relations in heme-containing oxygenases and peroxidases
TL;DR: Structural factors that influence functional properties are examined in the case of four heme enzymes and the importance of synthetic porphyrin models in understanding the properties of the protein-free metal center is emphasized.