Journal ArticleDOI
Mild hydrogen-transfer reductions using sodium hypophosphite
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This article is published in Journal of Organic Chemistry.The article was published on 1985-09-01. It has received 72 citations till now. The article focuses on the topics: Sodium hypophosphite & Hydrogenolysis.read more
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Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.
TL;DR: This Account discusses the previously neglected potential of these phosphinates as replacements of PCl3 for the preparation of organophosphorus compounds and examines the use of transition metal-catalyzed reactions such as cross-coupling and hydrophosphinylation for phosphorus-carbon bond formation.
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Recent advances in phosphorus-carbon bond formation: synthesis of H-phosphinic acid derivatives from hypophosphorous compounds
TL;DR: The work in this article summarizes the research conducted in our laboratory over the past five years, with a focus on the reactions of hypophosphorous acid derivatives, including room-temperature radical addition and palladium-catalyzed addition.
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Phosphorus‐Carbon Bond Formation: Palladium‐Catalyzed Cross‐Coupling of H‐Phosphinates and Other P(O)H‐Containing Compounds
TL;DR: Two generally applicable systems have been developed for the cross-coupling of P(O)H compounds with Csp2X and related partners as discussed by the authors, using a ligand/additive combination, typically either xantphos/ethylene glycol or 1,1′-bis(diphenylphosphino)ferrocene/1,2-dimethoxyethane, with diisopropylethylamine as the base.
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Synthesis of Monosubstituted Phosphinic Acids: Palladium-Catalyzed Cross-Coupling Reactions of Anilinium Hypophosphite
Journal ArticleDOI
Palladium-catalyzed phosphorus–carbon bond formation: cross-coupling reactions of alkyl phosphinates with aryl, heteroaryl, alkenyl, benzylic, and allylic halides and triflates
TL;DR: In this paper, the direct formation of H-arylphosphinates and related compounds can be accomplished using palladium catalysis, and the reactions of alkenyl and allylic halides are also described for the first time.