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Journal ArticleDOI

Modeling of reaction rate constants and selectivities in soybean oil hydrogenation

A. H. Chen, +2 more
- 01 Aug 1981 - 
- Vol. 58, Iss: 8, pp 816-818
TLDR
In this paper, a simple approach to model the rate constants and selectivities for soybean oil hydrogenation with nickel catalyst is presented, and the rate constant models were constructed on the basis of Arrhenius Law and Power series.
Abstract
A simple approach to model the rate constants and selectivities for soybean oil hydrogenation with nickel catalyst is presented. The rate constant models were constructed on the basis of Arrhenius Law and Power series. The parameters were temperature, hydrogen pressure, concentration of catalyst and agitation expressed in terms of power per unit volume of oil. The models agree with the general knowledge in hydrogenation and the data were fitted fairly well by the models.

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Journal ArticleDOI

Heterogeneous hydrogenation of vegetable oils: A literature review

TL;DR: In this paper, the authors present a comprehensive literature review on the kinetics of the hydrogenation and relevant transport and adsorption steps and conclude that future research should focus on the development of intrinsic kinetic rate expressions, which may subsequently contribute to develop new and improved hydrogenation catalysts.
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Catalysts and Network Modeling in Vegetable Oil Hydrogenation Processes

TL;DR: In this article, the authors considered the problem of hydrogenation of vegetable oils, which is one of the earliest commercial gas-liquid- solid heterogeneous catalytic processes and has attracted the attention of numerous scholars.
Journal ArticleDOI

The influence of the support on the properties of nickel catalysts for edible oil hydrogenation

TL;DR: In this paper, two silica-containing materials, diatomite and waterglass, have been used as supports of nickel catalysts for edible oil hydrogenation, and textural and structural characteristics of the supports and precursors have been studied by nitrogen sorption, scanning electron microscopy (SEM), infrared spectroscopy and X-ray powder diffraction (XRD).
Journal ArticleDOI

Sunflower oil hydrogenation on Pd in supercritical solvents: Kinetics and selectivities

TL;DR: In this paper, the partial hydrogenation of sunflower oil on a few supported Pd catalysts in supercritical (SC) dimethyl ether (DME) as reaction solvent was studied to obtain hydrogenates with low trans C 18:1 and stearic contents.
Journal ArticleDOI

Kinetic and Reactor Modeling of Catalytic Hydrotreatment of Vegetable Oils

TL;DR: In this paper, the development of mathematical models for the problem of bio-dieselization of vegetable oils has been studied in the context of renewable alternative to replace fossil fuels, and mathematical models have been developed.
References
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