Journal ArticleDOI
Molybdenum(VI) Dichloride Dioxide Catalyzed Synthesis of β-Keto Esters by C—H Insertion of Ethyl Diazoacetate into Aldehydes.
TLDR
In this paper, the synthesis of β-keto esters by condensing various aldehydes with ethyl diazoacetate was achieved by using molybde-num(VI) dichloride dioxide.Abstract:
Synthesis of β-keto esters by condensing various aldehydes with ethyl diazoacetate is achieved by using molybde-num(VI) dichloride dioxide. Aromatic, aliphatic, and heterocyclic aldehydes are successfully condensed with ethyl diazoacetate to obtain corresponding β-keto esters in high yields at room temperature.read more
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Silicon tetrachloride-induced regioselective reaction of Nbromosuccinimide with arylidenemalononitrile and with ¢-unsaturatedketones
TL;DR: In this paper, a mild method for the regioselective N-bromosuccinimide (NBS) addition to the olefinic double bond of benzalmalononitile derivatives using tetrachlorosilane (TCS) in acetonitrile as solvent at room temperature to produce 2bromo-2-((2,5-dioxopyrrolidin-1-yl)(aryl)methyl) malononitrile, in case of presence of donating group on benzene ring, substitution of
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Journal ArticleDOI
Molybdenum(VI) Dichloride Dioxide Catalyzed Synthesis of β-Keto Esters by C-H Insertion of Ethyl Diazoacetate into Aldehydes
TL;DR: In this paper, the synthesis of β-keto esters by condensing various aldehydes with ethyl diazoacetate was achieved by using molybde-num(VI) dichloride dioxide.