Journal ArticleDOI
Monocarbon carboranes II. Syntheses of carborane derivatives by reaction of group IV halides with cyanoboron hydrides
Frederick R. Scholer,Lee J. Todd +1 more
Reads0
Chats0
TLDR
This paper showed that carborane formation may proceed through a B 10 H 13 CNR − intermediate with either trimethylsilyl or trimethyltin chloride followed by base hydrolysis.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1968-10-01. It has received 15 citations till now. The article focuses on the topics: Carborane & Trimethylsilyl.read more
Citations
More filters
Journal ArticleDOI
A convenient cyanide-free “one-pot” synthesis of nido-Me3N-7-CB10H12 and nido-7-CB10H13−
Andrei S. Batsanov,Mark A. Fox,Andrés E. Goeta,Judith A. K. Howard,Andrew K. Hughes,John M. Malget +5 more
TL;DR: In this paper, the 11B NMR spectrum of nido-tBuMeHN-7-CB10H12 is explored as a function of pH, demonstrating exchange with nido tBuMeN- 7-CB 10H12−.
Journal ArticleDOI
Chemistry of Carba- closo -decaborate Anions [CB 9 H 10 ] – (Review)
A. V. Shmal’ko,Igor B. Sivaev +1 more
TL;DR: The state of the art of the chemistry of carba-closo-decaborate anions [1-CB9H10]− and [2-CB 9H10]- including their synthesis, substitution reactions of hydrogen atoms at carbon and boron atoms, as well as interconversion of various functional derivatives, is considered in this paper.
Journal ArticleDOI
Halogen derivatives of monocarbon carboranes, nido-7-Me3N-7-CB10H12, closo-2-Me3N-2-CB10H10 and closo-1-Me3N-1-CB11H11‡
TL;DR: Palladium catalysed substitution of iodine resulted in the nido and closo derivatives closo-8-CH2CHCH2-2-Ph-1-Me-3N- 1-CB11H9 and nido-4- CH2CH CH2-7-Me 3N- 7-CB10H11, which rationalise a mechanism for the boron insertion reactions.
Journal ArticleDOI
Ten-vertex monocarbaborane chemistry. Synthesis of carbon-substituted ligand derivatives 1-L-closo-1-CB9H9 and crystal and molecular structure of 1-(Me3N)-closo-1-CB9H9
TL;DR: In this article, the monocarbaborane ligand derivative (1-(H3N)-closo-1-CB9H9) has been isolated in 75% yield from the reaction between 6-(H 3N)-nido-6-CB 9H11 and Et3N·BH3 in tetrahydrofuran in the presence of NaBH4.
References
More filters
Journal ArticleDOI
Chemistry of Boranes. XIX.1 Derivative Chemistry of B10H10-2 and B12H12-2
Journal ArticleDOI