Journal ArticleDOI
N,N-Bis(trimethylstannyl)di-t-butylfluorsilylamin; ein sterisch fixiertes Molekül
TLDR
In this paper, the lithium salt of the aminofluorosilane (CMe3)2SiFNH2 reacts with Me3SnCl to give the mixed silyl- and stannyl-sbustituted amine.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1988-03-01. It has received 4 citations till now.read more
Citations
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Book ChapterDOI
Application of 119Sn NMR Parameters
TL;DR: In this paper, the impact of 119Sn nuclear magnetic resonance (NMR) parameters, determined either by 119Sn NMR or in the NMR spectra of other nuclei, on tin chemistry is remarkable.
Journal ArticleDOI
Tin organometallic compounds: classification and analysis of crystallographic and structural data: part 1. monomeric derivatives
Clive E. Holloway,Milan Melnik +1 more
Abstract: This review collects together the crystallographic data of organotin compounds by type and complexity, with a view to identifying correlations between properties and structure. Because of the large number of such structures, this first part deals only with monomeric derivatives, which covers almost one thousand structural determinations. While coordination numbers range from two to eight, for two and three coordination only tin(ll) compounds are found. All others are tin(IV) except for four examples with coordination number four, and ten with coordination number five. The predominant geometries are tetrahedral, trigonal bipyramidal, pseudo-octahedral and pentagonal bipyramidal. The most common C-donor ligands are methyl and phenyl. There are examples of distortion and structural isomerism. CONTENTS 0. ABBREVIATIONS
Journal ArticleDOI
Synthesis and Characterization of a Soluble, Highly Branched Organo-Silicon−Nitride Polymer
TL;DR: In this article, a highly soluble organopolysilazane was generated from the reaction of CySiCl3 with Li3N in diglyme, which is characterized by excellent solubility in all organic solvents, a highly economical method of synthesis, hyperbranched topology, and potential applicability to a wide range of R group modification.
References
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Journal ArticleDOI
Diisopropyl‐(2,4,6‐tri‐tert‐butylphenylimino)silan – ein sehr stabiles, freies Silaimin
Michael Hesse,Uwe Klingebiel +1 more
Journal ArticleDOI
Elementorganische Amine und Imine
TL;DR: In this paper, the Problematik reversibler and irreversibler (CH3)3)El-Ligandenplatzwechsel-prozesse (1,3-Wanderung) wird anhand trimethyl(IVa)element-substituierter Benzamidine, Diaminophosphine, Amino-IMINophosphorane, Sulfinamide and Aminosulfimine diskutiert.
Journal ArticleDOI
Acyclische und cyclische NH ? SiF‐Systeme – stufenweise Kondensation von (Fluorsilyl)aminen
Uwe Klingebiel,Norbert Vater +1 more
TL;DR: In this paper, a stepwise synthesis of cyclodi-and-trisilazanes (R2SiNH) via acyclic compounds is achieved from difluorosilanes and LiNH2 (R = CHMe2, CMe3).