Journal ArticleDOI
On the free-radical reaction of primary alcohols with formaldehyde
TLDR
The reaction of primary alcohols with formalin or paraformaldehyde initiated by t-butyl peroxide in a glass apparatus under atmospheric pressure leads to the formation of alkane-1,2-diols as mentioned in this paper.Abstract:
The reaction of primary alcohols with formalin or paraformaldehyde initiated by t-butyl peroxide in a glass apparatus under atmospheric pressure leads to the formation of alkane-1,2-diols.read more
Citations
More filters
Journal ArticleDOI
Mathematical simulation of the kinetics of radiation induced hydroxyalkylation of aliphatic saturated alcohols
Michael M. Silaev,L.T. Bugaenko +1 more
TL;DR: In this article, the authors reported on the development of the kinetics of radiation hydroxymethylation and hydroxypropylation chain processes relating to aliphatic saturated alcohols in the γ-radiolysis of the alcohol-unsaturated compound systems to give 1,2 and 1,4-diols respectively.
Journal ArticleDOI
Simulation of nonbranched chain processes for producing 1,2-alkanediols in alcohol-formaldehyde systems
TL;DR: In this article, a quasi-steady-state treatment is used to obtain kinetic equations that can describe the nonmonotonic (with a maximum) dependences of the formation rates of the products on the concentration of free (desolvated) dissolved formaldehyde.
Journal ArticleDOI
Competition Kinetics of the Non-branched-Chain Processes of Free Radical Addition to the C=C, C=O, and O=O Bonds of Molecules 1
TL;DR: In this paper, five reaction schemes are suggested for addition processes of free radicals to the multiple bonds of molecules, which include reactions competing with chain propagation through a reactive free radical, of which one is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length.
Journal ArticleDOI
Kinetics of Nonbranched-Chain Processes of the Free-Radical Addition to Molecules of Alkenes, Formaldehyde, and Oxygen with Competing Reactions of Resulting 1:1 Adduct Radicals with Saturated and Unsaturated Components of the Binary Reaction System
TL;DR: In this paper, five reaction schemes for the initiated non-branched-chain addition of free radicals to the multiple bonds of the unsaturated compounds are suggested. But none of the proposed schemes are suitable for the non-monotonic (peaking) dependences of the formation rates of the molecular products (1:1 adducts) on the concentration of an unsaturated component in binary systems.
Kinetic Equations of Free-Radical Nonbranched-Chain Processes of Addition
TL;DR: In this paper, the formation rate of the molecular addition products (1:1 adducts) as a function of concentration of the unsaturated component has a maximum, and five reaction schemes are suggested for this addition process.
References
More filters