Journal ArticleDOI
Organophosphinepalladium complexes as catalysts for vinylic hydrogen substitution reactions
H. A. Dieck,R. F. Heck +1 more
About:
This article is published in Journal of the American Chemical Society.The article was published on 1974-02-01. It has received 334 citations till now. The article focuses on the topics: Substitution reaction & Catalysis.read more
Citations
More filters
Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI
Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
TL;DR: This Review attempts to trace the historical origin of these powerful reactions, and outline the developments from the seminal discoveries leading to their eminent position as appreciated and applied today.
Journal ArticleDOI
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
TL;DR: A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki coupling reactions over the last 15 years as mentioned in this paper, and there are now many suggestions in the literature that narrow the scope of types of precatalyst that may be considered true catalysts in these coupling reactions.
Journal ArticleDOI
Selected patented cross-coupling reaction technologies.
Journal ArticleDOI
Carboxylic acids as substrates in homogeneous catalysis.
TL;DR: This review provides an overview of interesting catalytic transformations of carboxylic acids and a number of derivatives accessible from them in situ to provide an invitation to complement, refine, and use these new methods in organic synthesis.
Related Papers (5)
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more