Book ChapterDOI
Oxidation and Hydrogenation Reactions Catalyzed by Transition Metal Complexes Bearing N‐Heterocyclic Carbene Ligands
Ryohei Yamaguchi,Ken-ichi Fujita +1 more
- pp 1-26
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The article was published on 2014-10-18. It has received 1 citations till now. The article focuses on the topics: Metal–ligand multiple bond & Transition metal carbene complex.read more
Citations
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Cationic iridium complexes bearing imidazol-2-ylidene ligands as transfer hydrogenation catalysts
TL;DR: In this article, the synthesis and characterization of the PF6 and diazabutadienes complexes were reported. But their activity was not compared with that of the related cationic iridium(I) species.
References
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Journal ArticleDOI
Synthesis and structural chemistry of arene-ruthenium half-sandwich complexes bearing an oxazolinyl–carbene ligand
Macarena Poyatos,Aline Maisse-François,Stéphane Bellemin-Laponnaz,Eduardo Peris,Lutz H. Gade +4 more
TL;DR: In this paper, a series of directly connected oxazoline-imidazolium salts with silver(I) oxide and subsequent transmetallation with [Ru( p -cymene)Cl 2 ] 2 and anion exchange with KPF 6 cleanly gave the corresponding 2-oxazolinyl-( N -mesityl)imidrazolidene(chloro)ruthenium(II) half-sandwich complexes [RuCl(oxcarb)( p -cyclmene)]PF 6, two derivatives of which were characterized by X-
Journal ArticleDOI
Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes
TL;DR: In this paper, the authors showed that rhodium and iridium catalysts can be used as catalysts for racemization in the one-pot chemoenzymic dynamic kinetic resolution (DKR) of secondary alcohols.
Journal ArticleDOI
Stoichiometric and catalytic reactivity of the N-heterocyclic carbene ruthenium hydride complexes [Ru(NHC)(L)(CO)HCl] and [Ru(NHC)(L)(CO)H(η2-BH4)] (L = NHC, PPh3)
Victoria L. Chantler,Sarah L. Chatwin,Rodolphe Jazzar,Mary F. Mahon,Olly Saker,Michael K. Whittlesey +5 more
TL;DR: Compounds have been tested as catalysts for the hydrogenation of aromatic ketones in the presence of (i)PrOH and H2 and can be spectroscopically characterised.
Journal ArticleDOI
Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
TL;DR: Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens and the corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC rUThenium complexes.
Journal ArticleDOI
Syntheses and Structures of Ruthenium(II) N,S-Heterocyclic Carbene Diphosphine Complexes and their Catalytic Activity towards Transfer Hydrogenation
TL;DR: Two geometric isomers of 6 have been isolated and the structures of these products, which have been elucidated by single-crystal X-ray crystallography, show two structural types, I and II, depending on the relative dispositions of the ligands.
Related Papers (5)
Transition Metal-Catalyzed Reactions Using N-Heterocyclic Carbene Ligands (Besides Pd- and Ru-Catalyzed Reactions)
Thomas N. Tekavec,Janis Louie +1 more