Journal ArticleDOI
Palladium-assisted organic reactions-I. Application of the heck reaction to the preparation of 4-styrylisoquinoline derivatives
S.F. Dyke,M.J. McCartney +1 more
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The 4-mercurated derivatives of N-methylisocarbostyrils undergo insertion reactions with methyl acrylate and with styrenes in the presence of palladium acetate.About:
This article is published in Tetrahedron.The article was published on 1981-01-01. It has received 11 citations till now. The article focuses on the topics: Heck reaction & Organic reaction.read more
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Book ChapterDOI
4.3 – Vinyl Substitutions with Organopalladium Intermediates
TL;DR: For instance, double-bond rearrangement may occur when X is a halogen and the halogen acid produced by the reaction is not neutralized as it is formed by inclusion of a base as discussed by the authors.
Journal ArticleDOI
Cyclopalladated imines in synthesis 2 : a new synthesis of isoquinolines
I.R. Girling,David A. Widdowson +1 more
TL;DR: In this paper, reaction of cyclopalladated arylimines with acrylonitrile, followed by thermolysis gives isoquinolines by an electrocyclic ring forming process and a subsequent eliminative aromatisation step.
Journal ArticleDOI
Palladium assisted organic reactions: IV. A new isoquinoline ring synthesis☆
N. Barr,S.F. Dyke,S.N. Quessy +2 more
TL;DR: In this paper, a new synthesis of the isoquinoline ring with functionalised substituents at C(3) and C(4) was proposed, which constitutes a new synthesisation of the 3-carboxylate ring.
Journal ArticleDOI
Palladium assisted organic reactions. VI: A new method for the preparation of cyclopalladated benzalimines
P.W. Clark,S.F. Dyke +1 more
TL;DR: In this article, a new method for the preparation of cyclopalladated benzalimines is described, which consists of reacting the ortho-bromobenzalimine with bis(dibenzylideneacetone) palladium(0).
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives
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