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John M. Brown

Researcher at University of Oxford

Publications -  557
Citations -  15096

John M. Brown is an academic researcher from University of Oxford. The author has contributed to research in topics: Catalysis & Rhodium. The author has an hindex of 57, co-authored 554 publications receiving 14488 citations. Previous affiliations of John M. Brown include University of Seville & Karlsruhe Institute of Technology.

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MonographDOI

Rotational Spectroscopy of Diatomic Molecules

TL;DR: Brown and Carrington as discussed by the authors developed the theory behind the energy levels of diatomic molecules and then summarised the many experimental methods used to study their spectra in the gaseous state.
Journal ArticleDOI

The labeling of parity doublet levels in linear molecules

TL;DR: The rotational energy levels of diatomic and linear polyatomic molecules often occur in closely spaced pairs of opposite parity as discussed by the authors, and the lower levels of each pair usually form a characteristic set (for example, it may be possible to describe them all with a single energy level expression).
Journal ArticleDOI

Cellular differentiation hierarchies in normal and culture-adapted human embryonic stem cells

TL;DR: It is shown that the gene expression programmes of the adapted cells partially reflected their aberrant karyotype, but also resulted from a failure in X-inactivation, emphasizing the importance in adaptation of karyotypically silent epigenetic changes.
Journal ArticleDOI

Imidazo[1,5-a]pyridine: a versatile architecture for stable N-heterocyclic carbenes.

TL;DR: Rh(I) mono- and biscarbenes from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
Journal ArticleDOI

Mechanistic and synthetic studies in catalytic allylic alkylation with palladium complexes of 1-(2-diphenylphosphino-1-naphthyl)isoquinoline

TL;DR: In this article, a series of Pd allyl complexes are shown to be highly reactive catalysts for the reaction between (E,E)-1,3-diphenyl-2-propenyl acetate and dimethyl malonate ion; the enantiomer excess varies between 67% and 98% depending on how the reaction is conducted.