Journal ArticleDOI
Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides
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This article is published in Journal of the American Chemical Society.The article was published on 1994-06-01. It has received 662 citations till now. The article focuses on the topics: Palladium & Catalysis.read more
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C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals
TL;DR: This Review provides an overview of C-H bond functionalization strategies for the rapid synthesis of biologically active compounds such as natural products and pharmaceutical targets.
Journal ArticleDOI
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
TL;DR: A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki coupling reactions over the last 15 years as mentioned in this paper, and there are now many suggestions in the literature that narrow the scope of types of precatalyst that may be considered true catalysts in these coupling reactions.
Journal ArticleDOI
Selected patented cross-coupling reaction technologies.
Journal ArticleDOI
Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.
TL;DR: The conceptual basis and utility of the latest, "fourth-generation" palladium catalyst for the coupling of amines and related reagents with aryl halides is described and the effects of electronic properties on C-C and C-N bond-forming reductive elimination are similar.
Journal ArticleDOI
Development of Pd–Cu catalyzed cross-coupling of terminal acetylenes with sp2-carbon halides
TL;DR: The Pd-catalyzed cross coupling reactions between sp 2 -C halides and terminal acetylenes have been independently reported by Heck, Cassar and us in 1975 as mentioned in this paper.
Related Papers (5)
Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more