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Palladium(II) octaalkylporphyrinates: Synthesis and spectral properties
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TLDR
Palladium 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate (I) and its 5,15-diaza (II), diphenyl (III), and di(4-bromophenyl) (IV) derivatives were synthesized by the complex formation reaction of palladium(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide, and their spectral properties were studied as mentioned in this paper.Abstract:
Palladium 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate (I) and its 5,15-diaza (II), diphenyl (III), and di(4-bromophenyl) (IV) derivatives were synthesized by the complex formation reaction of palladium(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide, and their spectral properties were studied.read more
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Synthesis of Aza-, Oxa-, and Thiaporphyrins and Related Compounds.
TL;DR: This review will focus mainly on recent advances in the synthesis of aza-, oxa-, and thiaorphyrins and related compounds, including historically important examples.
Journal ArticleDOI
Free Base and Metal Complexes of 5,15-Diaza-10,20-dimesitylporphyrins: Synthesis, Structures, Optical and Electrochemical Properties, and Aromaticities
TL;DR: The obtained data show that replacement of the 5- and 15-methine carbons with nitrogen atoms alters the intrinsic properties of the porphyrin 18π system as follows: the coordination spheres at the N(4) core become contracted while keeping high planarity.
Journal ArticleDOI
A 3‐Pyridyl‐5,15‐Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals
TL;DR: Single-crystal X-ray diffraction analysis of 3-Pyridyl-5,15-diazaporphyrin nickel(II) unambiguously reveals the presence of a dative bond between the outer metal center and the meso-nitrogen atom.
Journal ArticleDOI
Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination.
TL;DR: Treatment of 10,20-dimesityl-5,15-diazaporphyrin and its nickel(ii) complex with a combination of AuBr3/AgOTf induced selective bromination on the mesityl groups can be employed for late-stage modification of the aryl substituents.
Journal ArticleDOI
Zinc(II) and Manganese(II) Oxalatopalladates as Precursors of Bimetallic Nanomaterials
I. A. Garkul,Andrey V. Zadesenets,Pavel E. Plyusnin,E. Yu. Filatov,Tatyana I. Asanova,D. V. Kozlov,Sergey V. Korenev +6 more
TL;DR: In this article, the thermal properties of [Zn(H2O)3(PdOx2)}2(μ-H2Os)2] · 4H 2O and [Mn3O4]n · nH 2Os have been studied in various atmospheres.
References
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Coordination Compounds of Porphyrins and Phthalocyanine
TL;DR: In this article, the physicochemical properties of natural and synthetic porphyrins, phthalocyanine and its polymers, and their numerous complexes are reviewed. And specific features of the processes of their formation and dissociation, the mechanisms of these processes, and conditions for further coordination on metalloporphyrin are discussed.
Journal ArticleDOI
The Infrared Spectra of Metallooctaethylporphyrins
TL;DR: The infrared spectra of octaethylporphyrins have been studied over the range 4000-100 cm−1 as mentioned in this paper, where the metal sensitive bands have been observed at about 980, 920, 340, 230, and 130cm−1.
Journal ArticleDOI
Phosphorescent Platinum/Palladium Coproporphyrins for Time-resolved Luminescence Microscopy
R.R. de Haas,R.P.M. van Gijlswijk,E. B. Van Der Tol,Jacky Theo Maria Veuskens,H. E. Van Gijssel,R.B. Tijdens,J. Bonnet,N.P. Verwoerd,Hans J. Tanke +8 more
TL;DR: The developed in situ detection technology is shown to be applicable not only in mammals but also in plants and suitable for detection of antigens and DNA targets in an autofluorescent environment.