Journal ArticleDOI
Physical properties and hydrogen-bonding in the system ethanol-2,2,2-trifluoroethanol
L.M. Mukherjee,Ernest Gruneald +1 more
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This article is published in The Journal of Physical Chemistry.The article was published on 1958-10-01. It has received 70 citations till now. The article focuses on the topics: 2,2,2-Trifluoroethanol & Molecule.read more
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A model for the interaction of trifluoroethanol with peptides and proteins
Rahul Rajan,Padmanabhan Balaram +1 more
TL;DR: A model is proposed for TFE interaction with peptides which involves an initial replacement of the hydration shell by fluoroalcohol molecules, a process driven by apolar interactions and favourable entropy of dehydration.
Journal ArticleDOI
Solvatochromism and thermochromism of rhodamine solutions
TL;DR: In this article, the position of the lactone-zwitterion equilibrium depends upon solvent-dye hydrogen bonding and solvent dielectric/polarizability properties.
Journal ArticleDOI
Solvent Effects on the Activation Rate Constant in Atom Transfer Radical Polymerization
TL;DR: Rate constants of activation (kact) for the reactions of tertiary alkyl halides with the ATRP catalyst CuIBr/1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) have been determined in 14 different solvents and the effect of increasing amounts of monomer in a solvent on the activation rate has been analyzed.
Journal ArticleDOI
Properties of 2,2,2-trifluoroethanol and water mixtures
Rajappa Chitra,Paul E. Smith +1 more
TL;DR: In this article, molecular dynamics simulations of 2,2,2-trifluoroethanol (TFE) and water mixtures of different composition were performed in an attempt to improve the atomic level understanding of the properties of TFE/water mixtures.