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Poly[[hexa-aqua-(μ(2)-fumarato-κO,O:O,O)bis-(μ(3)-maleato-κO,O:O:O)disamarium(III)] hexa-hydrate].

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TLDR
In this paper, the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atom from one fumarate ligand and three O atoms of three water mol-ecules.
Abstract
In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water mol-ecules. The fumarate ligand lies on an inversion center. Adjacent Sm(III) ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by inter-molecular O-H⋯O hydrogen bonds into a three-dimensional supra-molecular network.

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Journal ArticleDOI

A short history of SHELX

TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
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Structure validation in chemical crystallography

TL;DR: This paper reports on the current status of structure validation in chemical crystallography and describes the current state of research in this area.
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Disodium diaquabis(malonato-κ2O,O′)cobalt(II) monohydrate

TL;DR: In this paper, the Co atom is coordinated by four O atoms from two malonate ligands and two water mol-ecules in a distorted octahedral geometry, and two independent Na+ ions are coordinated by six and eight O atoms, respectively.
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Trisodium diaqua­bis(malonato-κ2O,O′)nickelate(II) chloride hexa­hydrate

TL;DR: In the title compound, Na3[Ni(C3H 2O4)2]Cl·6H2O, two crystallographically independent Ni atoms lie on centres of symmetry, each coordinated by four O atoms from two malonate ligands and by two water mol­ecules in a distorted octa­hedral geometry.