Polymer synthesis in non-ionic deep eutectic solvents
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TLDR
In this article, the use of non-ionic deep eutectic solvents (ni-DESs) as porogens in polymer synthesis was reported, and three ni-DES systems were deployed in the synthesis of a series of cross-linked copolymer monoliths comprised of a functional monomer, methacrylic acid (MAA) or hydroxyethylmethacrylate (HEMA), and a cross-linking monomer.About:
This article is published in Polymer Chemistry.The article was published on 2019-10-08 and is currently open access. It has received 17 citations till now. The article focuses on the topics: Methacrylic acid & Divinylbenzene.read more
Citations
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Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science.
Yeasmin Nahar,Stuart C. Thickett +1 more
TL;DR: Deep eutectic solvents (DESs) represent an emergent class of green designer polymers that find numerous applications in different aspects of chemical synthesis, including polymer formation, hydrogel design, porous monoliths, and molecularly imprinted polymers.
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Synthesis of magnetic poly (acrylic acid-menthol deep eutectic solvent) hydrogel: Application for extraction of pesticides
TL;DR: In this paper, a novel magnetic deep eutectic solvent (DES)-based polymeric hydrogel was synthesized via a facile and rapid (in 4min) thermal frontal polymerization, using acrylic acid-menthol DES (as a functional monomer), ammonium persulfate (as initiator), and acrylic acid -Fe3O4 nanoparticles (as cross-linker).
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Deep Eutectic Solvents and Multicomponent Reactions: Two Convergent Items to Green Chemistry Strategies
TL;DR: In this paper, the authors reviewed the state of the art of the use of deep eutectic solvents (DES) paying special attention to the role of reaction media in organic synthesis.
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A new type IV DES: a competent green catalyst and solvent for the synthesis of α,β-unsaturated diketones and dicyano compounds by Knoevenagel condensation reaction
TL;DR: In this paper, four new CeCl3·7H2O-based DESs were developed and their physical properties were studied in the Knoevenagel condensation reaction of dimedone/malononitrile with various aldehydes.
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Non-ionic deep eutectic solvents for membrane formation
Norafiqah Ismail,Jun Pan,Mahmoud Rahmati,Qian Wang,Denis Bouyer,Mohamed Khayet,Zhaoliang Cui,Naser Tavajohi +7 more
TL;DR: In this article , a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation, and three types of NIDES are synthesized and used to dissolve polyvinylidene fluoride (PVDF) polymer.
References
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Deep Eutectic Solvents (DESs) and Their Applications
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Deep eutectic solvents: syntheses, properties and applications
TL;DR: All works discussed in this review aim at demonstrating that Deep Eutectic Solvents not only allow the design of eco-efficient processes but also open a straightforward access to new chemicals and materials.
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Low-transition-temperature mixtures (LTTMs): a new generation of designer solvents.
TL;DR: A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low-transition-temperature mixtures (LTTMs).
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Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials
Daniel Carriazo,María Concepción Serrano,María C. Gutiérrez,Maria L. Ferrer,Francisco del Monte +4 more
TL;DR: The aim of this review is to provide an exposition of some of the most recent applications of deep-eutectic solvents (DESs) in the synthesis of polymers and related materials to encourage scientists to explore the promising perspectives offered by DESs.
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Recent advances in the application of deep eutectic solvents as sustainable media as well as catalysts in organic reactions
TL;DR: Deep eutectic solvents (DESs) have become more and more attractive in recent years due to their interesting properties and benefits, such as low cost of components, easy to prepare, tunable physicochemical properties, negligible vapor pressure, non-toxicity, biorenewability and biodegradability as mentioned in this paper.