Journal ArticleDOI
Preparation and properties of some cationic complexes of rhodium(I) and rhodium(III)
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This article is published in Journal of the American Chemical Society.The article was published on 1971-05-01. It has received 379 citations till now. The article focuses on the topics: Rhodium & Cationic polymerization.read more
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Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands
Armin Bader,Ekkehard Lindner +1 more
TL;DR: In this article, the authors classify O,P ligands: ether-phosphines and furylphosphine, β-ketophosphines, δ-ketophosphine and β-carboxylates, αphosphinosulphoxides and their complexes.
Journal ArticleDOI
Transition Metal Catalyzed Alkene and Alkyne Hydroacylation
TL;DR: Intermolecular Alkene Hydroacylation 3.2.1.
Journal ArticleDOI
Cationic iridium diolefin complexes as alkene hydrogenation catalysts and the isolation of some related hydrido complexes
TL;DR: In non-coordinating solvents, such as CH 2 Cl 2, the complexes [Ir(cod)L 2 ]PF 6 (I) and [Ir[cod]L(py)]PF 6(II) (cod 1,5-cyclooctadiene; py pyridine, L ǫ tertiary phosphine) are very active homogeneous hydrogenation catalysts for alkenes as discussed by the authors.
Journal ArticleDOI
Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts
Max R. Friedfeld,Michael Shevlin,Jordan M. Hoyt,Shane W. Krska,Matthew T. Tudge,Paul J. Chirik +5 more
TL;DR: From studies, base metal precatalysts have been discovered for the hydrogenation of functionalized and unfunctionalized olefins with high enantiomeric excesses, demonstrating the potential utility of more earth-abundant metals in asymmetric hydrogenation.
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Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins
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