Journal ArticleDOI
Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine
Henri B. Kagan,Dang-Tuan-Phat +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1972-09-01. It has received 917 citations till now. The article focuses on the topics: Rhodium & Butane.read more
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New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
Wenjun Tang,Xumu Zhang +1 more
TL;DR: The increasing demand to produce enantiomerically pure pharmaceuticals, agrochemicals, flavors, and other fine chemicals has advanced the field of asymmetric catalytic technologies, and asymmetric hydrogenation utilizing molecular hydrogen to reduce prochiral olefins, ketones, and imines has become one of the most efficient methods for constructing chiral compounds.
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BINAP: an efficient chiral element for asymmetric catalysis
Ryoji Noyori,Hidemasa Takaya +1 more
Journal ArticleDOI
Recent developments in the synthesis and utilization of chiral sulfoxides.
Journal ArticleDOI
Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis
TL;DR: In this article, it is shown that double asymmetric induction can be analyzed in terms of the single asymmetric reactions of each of the two chiral reactants, and a new strategy based on this rule for the predictable creation of new chiral centers is discussed and the use of this strategy for the synthesis of sugars and macrolides is presented.
Journal ArticleDOI
Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines
TL;DR: This review describes the recent developments of highly efficient catalytic asymmetric hydrogenation of enamides, and enamines and specifically focuses on the substrates because hydrogenation is highly dependent on the substrate although the chiral metal catalysts play a significant role.
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