Journal ArticleDOI
Ion pairing in transition-metal organometallic chemistry.
About:
This article is published in Chemical Reviews.The article was published on 2005-03-09. It has received 455 citations till now. The article focuses on the topics: Organometallic chemistry & Group 2 organometallic chemistry.read more
Citations
More filters
Journal ArticleDOI
The ONIOM Method and Its Applications
Lung Wa Chung,W. M. C. Sameera,Romain Ramozzi,Alister J. Page,Miho Hatanaka,Galina P. Petrova,Travis V. Harris,Travis V. Harris,Xin Li,Zhuofeng Ke,Fengyi Liu,Hai Bei Li,Lina Ding,Keiji Morokuma +13 more
TL;DR: This paper presents a meta-analyses of the proton-probes of Na6(CO3)(SO4)2, Na2SO4, and Na2CO3 of the response of the H2O/O2 “spatially aggregating substance,” which has the potential to alter the structure of the molecule and provide clues to the “building blocks” of DNA.
Journal ArticleDOI
Asymmetric ion-pairing catalysis.
Katrien Brak,Eric N. Jacobsen +1 more
TL;DR: This review describes developments in the burgeoning field of asymmetric ion-pairing catalysis with an emphasis on the insights that have been gleaned into the structural and mechanistic features that contribute to high asymmetric induction.
Journal ArticleDOI
Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts.
TL;DR: In this review, special attention will be given to supramolecular catalysts for which the observed catalytic activity and/or selectivity have been imputed to non-covalent interaction between the reaction partners.
Journal ArticleDOI
Determining accurate molecular sizes in solution through NMR diffusion spectroscopy
TL;DR: The methodological procedures that can be used to obtain accurate molecular sizes in solution from diffusion NMR spectroscopy, and how to take into account the size of the solute with respect to that of the solvent and its non-spherical shape using the appropriate correction factors in the frictional coefficient are reviewed.
References
More filters
Journal ArticleDOI
Ionic liquid (molten salt) phase organometallic catalysis.
TL;DR: The advent of water-soluble organometallic complexes, especially those based on sulfonated phosphorus-containing ligands, has enabled various biphasic catalytic reactions to be conducted on an industrial scale and might combine the advantages of both homogeneous and heterogeneous catalysis.
Journal ArticleDOI
Anion Recognition and Sensing: The State of the Art and Future Perspectives
Paul D. Beer,Philip A. Gale +1 more
TL;DR: Anion recognition chemistry has grown from its beginnings with positively charged ammonium cryptand receptors for halide binding to a plethora of charged and neutral, cyclic and acyclic, inorganic and organic supramolecular host systems for the selective complexation, detection, and separation of anionic guest species.
Journal ArticleDOI
Late-metal catalysts for ethylene homo- and copolymerization.
Journal ArticleDOI
Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
Journal ArticleDOI
Catalytic reactions in ionic liquids
TL;DR: The use of ionic liquids as novel reaction media may offer a convenient solution to both the solvent emission and the catalyst recycling problem, as well as in supercritical carbon dioxide.