Journal ArticleDOI
Preparation and spectroscopic studies of tri(p-tolyl)-tin(IV) compounds. X-ray crystal structure of the quinoline-N-oxide adduct of tri(p-tolyl)tin(IV) bromide
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TLDR
In this article, synthesis and spectroscopic data are presented for R3SnIV compounds, where R is predominantly p-tolyl, of the following types: R 3SnX·L (X = Cl, Br or NCS; L = neutral, monodentate oxygen donor), R 3snY (YH = 1,2,4-triazole, N-phenyl-N-benzoylhydroxamic, succinanilic, levulinic and hippuric acids) and [R3SnL2About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1986-09-09. It has received 39 citations till now. The article focuses on the topics: Tin(IV) bromide & Diphenylphosphine oxide.read more
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Crystal structure of tribenzyl(2-pyridinethiolato-N-oxide)tin(IV): a rare example of a square pyramidal organotin(IV) compound
TL;DR: Tribenzyl(2-pyridinethiolato-Noxide)tin(IV) as mentioned in this paper adopts a configuration displaced 91% from a trigonal bipyramid to a square pyramid along the Berry pseudorotation pathway.
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The synthesis and structural characterization of some triorganotin(IV) complexes of 2-{[(E)-1-(2-hydroxyaryl)alkylidene]amino}acetic acid. Crystal and molecular structures of Ph3Sn(2-OHC6H4C(H)=NCH2COO) and Me3Sn(2-OHC6H4C(CH3)=NCH2COO)
TL;DR: In this article, the crystal structures of triphenyltin 2-{[(E)-1-(2-hydroxyphenyl)methylidene]amino}acetate and trimethyltin have been characterized using 1H, 13C, 119Sn-NMR and IR spectroscopic techniques in combination with elemental analyses.
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Mössbauer and NMR studies of intramolecular coordination in thienyltetraorganotin(IV) compounds, and the x-ray crystal structure of {C,N-[3-(2-pyridyl)-2-thienyl]} tri(p-tolyl)tin(IV)
TL;DR: Tetraorganotin(IV) compounds containing the [3-(2-pyridyl)-2-thienyl] group have been synthesized and their structures examined by 119m Sn Mossbauer and NMR ( 119 Sn and 13 C modes) spectroscopic techniques, and in the case of compound 1 by X-ray analysis.
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Tin organometallic compounds: classification and analysis of crystallographic and structural data: part 1. monomeric derivatives
Clive E. Holloway,Milan Melnik +1 more
Abstract: This review collects together the crystallographic data of organotin compounds by type and complexity, with a view to identifying correlations between properties and structure. Because of the large number of such structures, this first part deals only with monomeric derivatives, which covers almost one thousand structural determinations. While coordination numbers range from two to eight, for two and three coordination only tin(ll) compounds are found. All others are tin(IV) except for four examples with coordination number four, and ten with coordination number five. The predominant geometries are tetrahedral, trigonal bipyramidal, pseudo-octahedral and pentagonal bipyramidal. The most common C-donor ligands are methyl and phenyl. There are examples of distortion and structural isomerism. CONTENTS 0. ABBREVIATIONS
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Structural chemistry of organotin carboxylates
TL;DR: A crystal structure study of nBu2Sn(O2CCH2SC6H5)2 reveals the compound to be monomeric with the tin atom situated on a 2-fold axis in a skew-trapezoidal bipyramidal geometry as mentioned in this paper.
References
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Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination
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The vibrational spectra of the formate, acetate, and oxalate ions
Kouichi Ito,H. J. Bernstein +1 more
TL;DR: In this paper, the infrared spectra of formate, acetate, and oxalate ions with depolarization ratios have been obtained for both the solid and aqueous solution.
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Recent japanese work on the chemistry of pyridine 1-oxide and related compounds
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Sulfoxides as ligands. ii. the infrared spectra of some dimethyl sulfoxide complexes
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13C and 119Sn NMR Study of some four- and five-coordinate triphenyltin(IV) compounds
TL;DR: In this paper, the 13C and 119Sn NMR spectra of four and five-coordinate triphenyltin(IV) compounds have been examined and the chemical shifts δ(119Sn) and the coupling constants 1J(119sn-13C) depend markedly on the coordination number of the tin atom and on the geometry of the coordination sphere.