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Journal ArticleDOI

Quantum mechanical approach for electroless plating process

TLDR
In this paper, a high speed electroless nickel plating bath with p-tolyl thiourea and diphenyl thiamourea as accelerators was developed.
Abstract
A high speed electroless nickel plating bath has been developed with p-tolyl thiourea and diphenyl thiourea as accelerators for electroless nickel plating process. The acceleration effect of the compounds was determined by weight gain and electrochemical method. Both compounds improved the rate of deposition to considerable extent by adsorbing strongly on the steel surface. The adsorption of the accelerators was found to obey Langmuir adsorption isotherm. The Arrhenius plot and quantum mechanical parameters further justified the impressive performance of accelerators through their effective adsorption on metal surface.

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Influences of different reinforcement particles on performances of electroless composites

TL;DR: In this article, the effects of different reinforcement particles on the morphology, composition, microstructure, microhardness, wear resistance and corrosion resistance of composites were investigated, and the results showed that the largest incorporation amount of particles in number density, the finest grains, the highest micro-hardness and the best wear resistance were found to occur on the silicon carbide reinforced coating.
Journal ArticleDOI

Effect of zwitterionic surfactant on tribological behaviour of electroless plating

TL;DR: In this article, the effect of zwitterionic surfactant on coating thickness, surface structure, adhesion, specific wear rate and microhardness was studied, and the results indicated that there was an improvement in the properties of coated substrate.
Journal ArticleDOI

Investigation of Al-induced electroless Sn film deposition on Cu substrate

TL;DR: In this paper, the galvanic couple between Cu-Al initiates the metal reduction reaction from a bath without traditional reducing agent and additives, and a sodium borohydride as a chemical reducing agent was also added for codeposition of boron.
Journal ArticleDOI

Metallization of PLA plastics prepared by FDM-RP process and evaluation of corrosion and hardness characteristics

TL;DR: In this article, an attempt has been made in this work to develop copper coatings with enhanced corrosion and hardness properties on PLA plastics prepared by FDM-RP process, which can find as substitute for metal parts used in automobile components.
Journal ArticleDOI

Electroless plating of copper on Al2O3 and its heat treatment behaviour

TL;DR: In this article, a non-noble pretreatment was used to improve the surface properties of electroless copper plating on Al2O3 substrate, where the surface exhibits granular distribution and the particles are closely bound.
References
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Journal ArticleDOI

Electrochemical and DFT studies of β-amino-alcohols as corrosion inhibitors for brass

TL;DR: In this article, the electrochemical performance of 1-diethylamino-propan-2-ol (EAP) and 1-3-bis-deterministic dihydramino-polypropan 2 (DEAP) for brass in simulated atmospheric water is evaluated by potentiodynamic curves and electrochemical impedance spectroscopy (EIS).
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Enhanced corrosion resistance of mild steel in normal sulfuric acid medium by 2,5-bis(n-thienyl)-1,3,4-thiadiazoles: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies

TL;DR: In this paper, the inhibitive action of some thiadiazole derivatives, namely 2,5-bis(2-thienyl)-1,3,4-THIADIA (2-TTH), against the corrosion of mild steel in 0.5 m H 2 SO 4 solution has been investigated using weight loss measurements, Tafel polarisation and electrochemical impedance spectroscopy (EIS) techniques.
Journal ArticleDOI

Corrosion inhibition of mild steel in hydrochloric acid solution by some double Schiff bases

TL;DR: In this article, the effect of double Schiff bases on the corrosion of mild steel in 2M HCl has been studied by polarization, electrochemical impedance spectroscopy (EIS) and weight loss measurements.
Journal ArticleDOI

A preliminary investigation of corrosion inhibition of mild steel in 0.5 M H2SO4 by 2-amino-5-(n-pyridyl)-1,3,4-thiadiazole: Polarization, EIS and molecular dynamics simulations

TL;DR: In this article, the performance of APTD on iron surface obeys the Langmuir isotherm, and the molecular dynamics simulations show that 4-APTD has a higher binding energy than that of 3-APtd.
Journal ArticleDOI

Some benzotriazole derivatives as corrosion inhibitors for copper in acidic medium: Experimental and quantum chemical molecular dynamics approach

TL;DR: In this paper, three benzotriazole derivatives namely, 1-(Phenylsulfonyl)-1H-benzotitriazole (PSB), 1-(3-Pyridinylsulfononyl) 1H-Benzotriaxole (3PSB) and 1-(2-pyridinyl-polysilicon-sulfonel)-poly(2PSB)) have been investigated for the corrosion of copper in 1M HNO3 at different concentrations at 25°C using chemical (weight
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