Journal ArticleDOI
Reversible oxidative addition of triphenylphosphine to zero-valent nickel and palladium complexes
Darryl R. Fahey,John E Mahan +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1976-07-01. It has received 91 citations till now. The article focuses on the topics: Triphenylphosphine & Palladium.read more
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Preparation and x-ray crystal structure of [Pd2(μ-O2CMe)2(C6H5)2(PPh3)2], a binuclear acetate-bridged palladium(II) phenyl complex formed by PC bond cleavage of triphenylphosphine
TL;DR: The binuclear complex [Pd2(μ-O2CMe)2 (C6H5)2(PPh3)2] was formed when Pd3(O2cMe)6] reacts with PPh3 in methanol as discussed by the authors.
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The thermal formation of bialkyls from alkylmetals
Björn Åkermark,Anders Ljungqvist +1 more
TL;DR: In this paper, the thermal decomposition of neophyl transition metal complexes has been investigated, in particular, the products of reductive elimination and the symmetry aspects of this reaction, and a number of other dimeric products were formed via routes which must involve transmetallation, α-elimination and, in a few cases, radical formation.
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13C and proton nuclear magnetic resonance spectra of trans‐[arylbromobis(triethyl phosphine)palladium(II)] and related compounds. The π‐donor ability of the Ni(PEt3)2X, Pd(PEt3)2X and Pt(PEt3)2X groups
TL;DR: In this article, the mean Δ(δ)C values induced on the ArH by the introduction of the PdBr(PEt3)2 substituent are found to be 26.13C and 7.9C, respectively.
Journal ArticleDOI
Formation of diaryls by thermal decomposition of rhodium(I) triarylphosphine complexes
TL;DR: In this article, it was assumed to involve dissociation of RhCl(PPh 3 ) 3 into PPh 3 and solvated RhClCl(pph 3 ) 2 followed by oxidative addition of the liberated phosphine to the latter bis-triphenylphosphine compound.
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Novel Poly[3-(p-substituted)benzoyl-2,5-thiophenes] via Nickel(0)-Catalyzed Coupling Polymerization
Jie Wang,Valerie V. Sheares +1 more
TL;DR: In this paper, three poly[3-(p-substituted)benzoyl-2,5thiophene]s (Ib, IIb, and IIIb) were successfully prepared via nickel(0)-catalyzed coupling polymerization.