Journal ArticleDOI
Reversible oxidative addition of triphenylphosphine to zero-valent nickel and palladium complexes
Darryl R. Fahey,John E Mahan +1 more
About:
This article is published in Journal of the American Chemical Society.The article was published on 1976-07-01. It has received 91 citations till now. The article focuses on the topics: Triphenylphosphine & Palladium.read more
Citations
More filters
Journal ArticleDOI
Reaction of Coordinated Phosphines. V. Aryl and Alkyl Transfer from Tertiary Phosphine to Transition Metal
TL;DR: A carbon-phosphorus bond cleavage was observed in the reaction of MCl2(PR3)2 (M=Ni, Co, or Pd, R=Ph, n-C8H17) with p-tolyllithium, ptolylmagnesium halide, lithium aluminum hydride, or magnesium amalgam, and the reactivity was most pronounced with Ni followed by Co and Pd.
Journal ArticleDOI
Stoichiometric and Catalytic Reactivity of Ni(6-Mes)(PPh3)2
TL;DR: The three-coordinate Ni(0) N-heterocyclic carbene complex Ni(6-Mes)(PPh3)2 (1; 6Mes = 1,3-bis(2,4,6-trimethylphenyl)-3, 4,5,6,tetrahydropyrimidin-2-ylidene) is formed in the reaction of Ni(cod)2 with a 1:2 mixture of 6-mes and PPh3 as discussed by the authors.
Journal ArticleDOI
Unsymmetrical platinum(II) phosphido derivatives: oxidation and reductive coupling processes involving platinum(III) complexes as intermediates.
Irene Ara,Juan Forniés,Consuelo Fortuño,Susana Ibáñez,Antonio Martín,Piero Mastrorilli,Vito Gallo +6 more
TL;DR: The X-ray diffraction structures of complexes 4, 5, 6, 9, and 11 have been studied and an unprecedented shielding of the (195)Pt nuclei upon passing from Pt(II) to Pt(III).
Journal ArticleDOI
Stability of phosphines under hydroformylation conditions
Toshiyasu Sakakura,Toshiaki Kobayashi,Teruyuki Hayashi,Yasujiro Kawabata,Masato Tanaka,Ikuei Ogata +5 more
TL;DR: The ability of metal carbonyls to cleave the PC bonds was found to be Rh > Co > Ru in the presence of a rhodium, ruthenium, or cobalt carbonyl as discussed by the authors.
Journal ArticleDOI
Synthetic Applications of Transition-Metal-Catalyzed C-P Bond Cleavage.
Lili Wang,Hui Chen,Zheng Duan +2 more
TL;DR: This review provides an account of the state of the art in the field of catalytic activations and transformations of carbon-phosphorus bonds within the coordination sphere of transition metals and highlights the future potential of these reactions in organic synthesis.