Journal ArticleDOI
Rhodium and molybdenum complexes as catalysts for conversion of nitrobenzene and aliphatic alcohols to alkylquinolines
William J. Boyle,Frank Mares +1 more
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This article is published in Organometallics.The article was published on 1982-07-01. It has received 29 citations till now. The article focuses on the topics: Nitrobenzene & Rhodium.read more
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Heterogeneous catalysis for the direct synthesis of chemicals by borrowing hydrogen methodology
TL;DR: In this paper, a review summarizes recent examples of hydrogen transfer-type reactions using supported transition metal catalysts with special emphasis on the direct synthesis of chemicals by borrowing hydrogen methodology, and the highlighted reactions are: (1) transfer hydrogenation of carbonyl compounds, (2) transfer dehydrogenation of alcohols, (3) N-alkylation of amines or NH3 with alcohols.
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Catalytic synthesis of isocyanates or carbamates from nitroaromatics using Group VIII transition metal catalysts
TL;DR: A review of catalyzed carbonylation of nitroaromatic compounds can be found in this article, where the most active catalytic systems developed for both direct and indirect isocyanate transformations are described.
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A novel synthesis of substituted quinolines using ring-closing metathesis (RCM): its application to the synthesis of key intermediates for anti-malarial agents
TL;DR: In this paper, a method for synthesizing substituted quinolines using ruthenium-catalyzed ring-closing metathesis as a key step has been developed.
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Oxidative transformation of aryls using molybdenum pentachloride
TL;DR: Molybdenum pentachloride combines a strong Lewis acid character with an unusually high oxidation potential creating a powerful reagent for oxidative transformations, and represents a unique and easily available reagent.
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Synthesis of quinolines by ruthenium-catalyzed heteroannulation of anilines with 3-amino-1-propanol
TL;DR: Anilines react with 3-amino-1-propanol in dioxane in the presence of a catalytic amount of a ruthenium catalyst and tin(II) chloride dihydrate together with a hydrogen acceptor to afford the corresponding quinolines in moderate yields.