Journal ArticleDOI
Rotating-disc electrode voltammetry. The catalytic mechanism (EC′) and its nuances
Richard G. Compton,Michael J. Day,Laing Mark,Richard J. Northing,James I. Penman,Andrew M. Waller +5 more
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TLDR
The various mechanistic nuances of the catalytic mechanism have been considered and it has been shown that steady-state rotating-disc voltammetry alone can discriminate between almost all of the various pathways considered.Abstract:
The various mechanistic nuances of the catalytic (EC′) mechanism have been considered and it has been shown that steady-state rotating-disc voltammetry alone can discriminate between almost all of the various pathways considered. This deduction has been illustrated with reference to, first, the oxidation of the acetate anion in acetonitrile solution by means of the electrogenerated radical cation of tris(p-bromophenyl)amine and secondly, to the reduction of t-butyl bromide, in the same solvent, mediated through the radical anion of fluoranthene.read more
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Journal ArticleDOI
Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles
TL;DR: Two diimine-dioxime complexes were identified as exhibiting catalytic onset at comparatively low overpotentials relative to other reported homogeneous cobalt and nickel electrocatalysts in aqueous solution.
Journal ArticleDOI
Cyclic Voltammetry of the EC′ Mechanism at Hemispherical Particles and Their Arrays: The Split Wave
TL;DR: In this article, the effect of the concentration of reactant species "X" on the split-wave phenomenon in the forward scan of a cyclic voltammogram was investigated.
Journal ArticleDOI
Homogeneous catalysis of electrochemical reactions: Mechanistic resolution via rotating-disc electrode voltammetric waveshape analysis
TL;DR: In this paper, the shape of the current-voltage curves at a rotating disc electrode have been calculated for various nuances of the catalytic (EC') mechanism, and the halfwave potential is found to be highly sensitive to the disc rotation speed and the concentrations of mediator and substrate employed.
Journal ArticleDOI
Novel amperometric sensor for the detection of the anaesthetic gases isoflurane and nitrous oxide
TL;DR: In this paper, a gas phase sensor for the detection of the anaesthetic isoflurane is described, which consists of a channel electrode flow cell with a gas-permeable membrane located immediately upstream of a detector electrode.
Journal ArticleDOI
Analysis of the steady-state behavior of pseudo-first-order EC-catalytic mechanism at a rotating disk electrode
TL;DR: In this paper, an analytical method is applied to solve a system of convection-diffusion equations in the pseudo-first-order EC-catalytic mechanism at a rotating disk electrode.
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