Journal ArticleDOI
Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture
Reads0
Chats0
About:
This article is published in Journal of the American Chemical Society.The article was published on 1996-03-13. It has received 995 citations till now. The article focuses on the topics: Transfer hydrogenation & Formic acid.read more
Citations
More filters
Journal ArticleDOI
Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
Journal ArticleDOI
Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo‐ and Stereoselective Hydrogenation of Ketones
Ryoji Noyori,Takeshi Ohkuma +1 more
TL;DR: The newly devised [RuCl(2)(phosphane)(2)(1,2-diamine)] complexes are excellent precatalysts for homogeneous hydrogenation of simple ketones which lack any functionality capable of interacting with the metal center.
Journal ArticleDOI
Catalytic activities of Schiff base transition metal complexes
K.C. Gupta,Alekha Kumar Sutar +1 more
TL;DR: A review of the catalytic activity of metal complexes of binaphthyl compounds and their combinations with salen Schiff base is presented in this paper, where the pyridyl bis (imide) and pyridine bis(imine) complexes of cobalt(II), iron(II) ions have been used as catalysts in the polymerization of ethylene and propylene.
Journal ArticleDOI
Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes
TL;DR: In this article, the authors classified the catalytic cycles for the H2-hydrogenation (H) and transfer hydrogenation (T) of CO and cN bonds catalyzed by over 100 ruthenium hydride complexes in organic and aqueous media.
References
More filters
Journal ArticleDOI
Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes
Journal ArticleDOI
Asymmetric catalytic reduction of carbonyl compounds using C2 symmetric diamines as chiral ligands
TL;DR: In this paper, the catalytic asymmetric reduction of prochiral ketones by hydride transfer using various C 2 symmetric chiral diamines as ligands and rhodium complexes is studied.
Journal ArticleDOI
Enantioselective catalytic reduction of ketones using C2-symmetric diamines as chiral ligands
TL;DR: In this article, the catalytic enantioselective reduction of various prochiral ketones using C 2 -symmetric diamines as ligands was reported, and up to 99% e.g. at 100% conversion are obtained.
Journal ArticleDOI
Chlorosulfenylated Carbonic Acid Derivatives
G. Zumach,E. Kühle +1 more
TL;DR: In this paper, the synthesis of chlorocarbonylsulfenyl chloride and its imino analogs is discussed, and the chemical behavior of these bifunctional compounds is illustrated for selected examples.
Journal ArticleDOI
Schiff bases as added chiral ligands for the [Ru(η6-C6H6)Cl2]2 catalysed hydrogen-transfer reduction of ketones with 2-propanol
Pavel Krasik,Howard Alper +1 more
TL;DR: Ruthenium complexes generated in situ from [Ru(C6H6)Cl2]2 and chiral Schiff bases [derived from(1R,2R)-diaminocyclohexane] catalyse asymmetric hydrogen-transfer reduction of alkyl aryl ketones by 2-propanol to give the (S)-alcohol in up to 40% ee.