Journal ArticleDOI
Shear Creep Studies of Narrow-Distribution Poly(cis-isoprene)
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This article is published in Macromolecules.The article was published on 1971-03-01. It has received 52 citations till now. The article focuses on the topics: Isoprene & Creep.read more
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Journal ArticleDOI
Packing Length Influence in Linear Polymer Melts on the Entanglement, Critical, and Reptation Molecular Weights
TL;DR: In this article, the entanglement molecular weight for a polymer melt, Me, is related by a power law to p, the packing length of the polymer species, and the observed and predicted values of Mr for two species, 1,4-polybutadiene and polyisobutylene, have been found to agree, within the uncertainties, with the projected values.
Journal ArticleDOI
Entanglement interactions in polymers and the chain contour concentration
W.W. Graessley,S.F. Edwards +1 more
TL;DR: In this paper, it was shown that the species dependence and the concentration dependence are related, and that to a first approximation both are manifestations of a universal law relating a mechanical interaction density, measured by G 0 N kT to the length of uncrossable chain contour per unit volume.
Book ChapterDOI
Chain Dimensions and Entanglement Spacings
TL;DR: In this article, the authors investigated the relationship between chain entanglement and tube diameter, and found that entanglements and tube diameters are correlated with temperature and critical molecular weight.